Journal ArticleDOI
Novel Phthalocyanines with Aza Crown Ether Moieties
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TLDR
In this article, a monoaza crown ether substituted (phthalocyaninato)copper (II) complex and its water-soluble quaternary ammonium salt were prepared from the corresponding dibromomonoaza Crown ether derivative 1 and CuCN in pyridine.Abstract:
A monoaza crown ether substituted (phthalocyaninato)copper(II) complex 2 and its water-soluble quaternary ammonium salt 3 were prepared from the corresponding dibromomonoaza crown ether derivative 1 and CuCN in pyridine.read more
Citations
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Conducting Stacked Metallophthalocyanines and Related Compounds
Michael Hanack,Manuela Lang +1 more
Journal ArticleDOI
Synthetic pathways to water-soluble phthalocyanines and close analogs
TL;DR: The different types of water-soluble phthalocyanines are presented and their synthesis is reviewed in this article, where the synthesis process is described in detail and the synthesis is discussed.
Journal ArticleDOI
Octakis(alkylthio)-substituted phthalocyanines and their interactions with silver(I) and palladium(II) ions
Ayşe Gül Gürek,Özer Bekaroǧlu +1 more
TL;DR: In this article, metal-free phthalocyanines and metal phthalochemicals carrying eight alkylthio-groups on peripheral positions have been synthesized from 4,5-bis(alkylthio)phthalonitrile and 1,8-diazabicyclo[5.0]undec-7-ene (dbu) or the corresponding anhydrous metal salt [NiCl2, CuCl, CoCl2 or Zn(O2CMe)2].
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Synthesis and coordination chemistry of unsymmetrical tetraazaporphyrins containing single oxathia- and thiacrown substituents
TL;DR: The oxathia-and thiaether-crowned porphyrazines were found to coordinate Ag(I) and HgCl 2, though all complexes suffered poor solubility and complexes with the latter were unstable in polar media as mentioned in this paper.
References
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Journal ArticleDOI
Ion channel containing mesophases: structural characteristics of condensed phases of crown-ether-substituted phthalocyanines
TL;DR: A copper complex of a phthalocyanine substituted with four benzo-15-crown-5 1,Cu and the corresponding dihydrogeno-derivative 1,H2 were synthesized X-ray determinations at small angles.
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Synthesis of monoaza crown ethers from N,N-di(oligo(oxyalkylene))amines and oligoethylene glycol di(p-toluenesulfonates) or corresponding dichlorides.
TL;DR: In this article, a one-step reaction between diethanolamine or N,N-di[oligo(oxyethylene)]amines and oligoethylene glycol di(p-toluenesulfonates) or corresponding dichlorides in t-butyl alcohol/dioxane in the presence of sodium or potassium tbutoxide is described.
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Lariat ethers. 3. Macrocylic polyethers bearing donor groups on flexible arms attached at a nitrogen pivot point
TL;DR: The binding of lariat ethers utilizing a nitrogen pivot atom for the donor sidearm is enhanced considerably relative to the carbon-based systems and this may be explicable in terms of diminished “sidedness” as discussed by the authors.
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Synthesis and Properties of a (Phthalocyaninato)copper(II) Complex Symmetrically Substituted with Eight Crown Ethers
TL;DR: In this paper, a soluble (phthalocyaninato)copper (II) complex containing eight symmetrical benzo-15-crown-5 substituents was synthesized from quinoline or pyridine.