Journal ArticleDOI
Nucleophilic borohydride: selective reductive displacement of halides, sulfonate esters, tertiary amines, and N,N-disulfonimides with borohydride reagents in polar aprotic solvents
Robert O. Hutchins,Duraisamy Kandasamy,Frank J. Dux,Cynthia A. Maryanoff,David. Rotstein,Barry Goldsmith,William Burgoyne,Frank Cistone,Joseph Dalessandro,Joseph Puglis +9 more
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This article is published in Journal of Organic Chemistry.The article was published on 1978-05-01. It has received 115 citations till now. The article focuses on the topics: Borohydride & Sulfonate.read more
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2′-C-Methyluridine phosphoramidite: a new building block for the preparation of RNA analogues carrying the 2′-hydroxyl group
TL;DR: A new stereoselective synthesis of 2′-C-methyluridine is expected to generate RNA analogues potentially useful in applications where proper RNA folding is required since the 2-hydroxyl group is conserved.
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Ionic and organometallic reductions with N-heterocyclic carbene boranes.
Qianli Chu,Malika Makhlouf Brahmi,Andrey Solovyev,Shau-Hua Ueng,Dennis P. Curran,Max Malacria,Louis Fensterbank,Emmanuel Lacôte +7 more
TL;DR: N-Heterocyclic carbene-borane complexes such as depicted are neutral, organic soluble analogues of borohydride anions with a weak hydridic character compatible with organometallic catalysis, applicable for surgical reductions in complex, multifunctional molecules.
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Reductive displacement of allylic acetates by hydride transfer via catalytic activation by palladium(0) complexes
TL;DR: In this paper, allylic acetates are reduced to alkenes by reductive displacement by hydride reagents via catalytic activation with Pd(0) complexes.
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Synthetically useful reactions with nickel boride. a review
Jitender M. Khurana,A. Gogia +1 more
TL;DR: In this article, the authors present a review of the use of NICKEL BORIDE in the context of organic preparation and procedures, and present a discussion of the most useful reactions with it.
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Wet THF as a Suitable Solvent for a Mild and Convenient Reduction of Carbonyl Compounds with NaBH4
Behzad Zeynizadeh,Tarifeh Behyar +1 more
TL;DR: In this paper, the reduction of carbonyl compounds such as aldehydes, ketones, conjugated enones, acyloins, and α-diketones to their corresponding alcohols was performed at room temperature or under reflux condition.