Journal ArticleDOI
Octahedral metal carbonyls. XXI. Carbonyl and metal-carbon stretching spectra of monosubstituted group VIB metal carbonyls☆☆☆
R.A. Brown,Gerard R. Dobson +1 more
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TLDR
In this paper, the infrared spectra in solution of thirty-seven complexes of the type LM(CO) 5 (L = Lewis base; M = Cr Mo, W) have been recorded in the regions 2100-1800 and 700-300 cm −1.About:
This article is published in Inorganica Chimica Acta.The article was published on 1972-01-01. It has received 92 citations till now. The article focuses on the topics: Lewis acids and bases & Metal carbonyl.read more
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Metal–dihydrogen and σ-bond coordination: the consummate extension of the Dewar–Chatt–Duncanson model for metal–olefin π bonding
TL;DR: In this article, the authors delineate the principles of σ-bond coordination and activation inspired by the Dewar-Chatt-Duncanson model and illuminates the often-spectacular interplay between theory and experiment in this field.
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Organonitrile complexes of transition metals
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Coordination chemistry of stibine and bismuthine ligands
TL;DR: The synthesis of the common monodentate and bidentate stibines and bismuthines, and of multidentates containing one or more antimony or Bismuth donor are briefly reviewed in this article.
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Journal ArticleDOI
Hard and soft acids and bases
TL;DR: In this paper, the rate data for the generalized nucleophilic displacement reaction were reviewed, and the authors presented a method to estimate the rate of the generalized displacement reaction in terms of the number of nucleophiles.
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A scale of electronegativity based on electrostatic force
A.L. Allred,Eugene G Rochow +1 more
TL;DR: In this article, an equation for the evaluation of electronegativity from the force of attraction between a nucleus and an electron from a bonded atom was presented, and the electronegativities of forty-four elements were calculated.
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Vibrational Spectra and Bonding in Metal Carbonyls. I. Infrared Spectra of Phosphine-substituted Group VI Carbonyls in the CO Stretching Region
C. S. Kraihanzel,F. A. Cotton +1 more
Related Papers (5)
Approach to the separation of inductive and mesomeric effects in complexes of the types LMn(CO)5 and LMo(CO)5
Vibrational Spectra and Bonding in Metal Carbonyls. I. Infrared Spectra of Phosphine-substituted Group VI Carbonyls in the CO Stretching Region
F. A. Cotton,C. S. Kraihanzel +1 more