Journal ArticleDOI
On the Detonation Characteristics of CHNO‐Type Condensed Explosives. A parameter study
V. Swaminathan,S. Rajagopalan +1 more
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In this article, the authors carried out a parametric study which takes into consideration the variations of the detonation characteristics such as CJ pressure, CJ temperature, velocity of detonation (VOD), and gas volume of CHNO-based condensed explosive systems in connection with the changes in input parameters like loading density and heat of formation of the explosive in question.Abstract:
The object of the present paper is to carry out a parametric study which takes into consideration the variations of the detonation characteristics such as CJ pressure, CJ temperature, velocity of detonation (VOD), and gas volume of CHNO-based condensed explosive systems in connection with the changes in input parameters like loading density and heat of formation of the explosive in question. Meaningful equations which describe adequately the interrelationships between the parameters were derived for a typical CHNO-type explosive. The study is likely to be of considerable help in determining the variations in the magnitudes of the detonation parameters corresponding to a given change in the relevant input characteristics. The results of such studies should also be important in estimating the uncertainty of a parameter, like VOD, arising from the uncertainty in the heat of formation of the explosive which is often determined experimentally and whose values is often of questionable validity. The principal features that emerge from the investigations in this paper are: (1) while CJ pressure and VOD tend to increase sizably with the loading density of the explosive, CJ temperature and CJ volume decrease with an increase in the loading density; and (2) all the four parameters, viz., CJ pressure, CJ temperature, VOD, and CJ volume increase, however, being of a marginal nature, barring the CJ temperature whose variations with the heat of formation are not insignificant.read more
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Journal ArticleDOI
The Chemistry of Detonations. IX. Some observations regarding a computer based parametric study of detonation characteristics of CHNO explosives
References
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Computer Program for Calculation of Complex Chemical Equilibrium Compositions and Applications II. Users Manual and Program Description. 2; Users Manual and Program Description
Bonnie J. McBride,Sanford Gordon +1 more
Computer Program for Calculation of Complex Chemical Equilibrium Compositions, Rocket Performance, Incident and Reflected Shocks, and Chapman-Jouguet Detonations. Interim Revision, March 1976
B. J. Mcbride,S. Gordon +1 more
TL;DR: In this paper, a detailed description of the equations and computer program for computations involving chemical equilibria in complex systems is given, and a free-energy minimization technique is used.
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