On the mechanism of transfer of sodium ion across the nitrobenzene/water interface facilitated by dibenzo-18-crown-6
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In this article, the site of ionophore-ion complex formation is investigated in the organic phase (EC), in the aqueous phase (CE), or at the interface (E) in the transfer facilitated by dibenzo-18crown-6 of sodium ion across the nitrobenzene/water interface.Abstract:
The question of the site of ionophore–ion complex formation, whether it is in the organic phase (EC), in the aqueous phase (CE), or at the interface (E), in the transfer facilitated by dibenzo-18-crown-6 of sodium ion across the nitrobenzene/water interface was studied by kinetic analysis of the ion transfer using a.c. polarographic method. The results indicate that the interface reaction mechanism (E) is the most probable of the three.read more
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References
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Reaction Rates in Ionic Solutions
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Electrochemical polarization phenomena at the interface of two immiscible electrolyte solutions
TL;DR: The faradaic and non-faradaic processes taking place at the interface of two immiscible electrolyte solutions have been compared with analogous processes occurring at interface metal-electrolyte solution as discussed by the authors.
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Charge transfer between two immiscible electrolyte solutions part VIII. Transfer of alkali and alkaline earth-metal cations across the water/nitrobenzene interface facilitated by synthetic neutral ion carriers☆
TL;DR: In this paper, a single-step charge transfer model was proposed to solve the problem of facilitating the transfer of proton, alkali and alkaline earth-metal cations across the water/nitrobenzene interface.
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A.c. polarographic study of ion transfer at the water/nitrobenzene interface
TL;DR: In this paper, the transfer of tetramethylammonium (TMA+) ion across the interface between LiCl aqueous solution and a 0.1 mol dm−3 tetrabutyammonium tetraphenylborate nitrobenzene solution was investigated by means of phase-selective a.c. polarography.
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Facilitated ion transfer across the water/nitrobenzene interface Theory for single-scan voltammetry applied to a reversible system☆
TL;DR: In this paper, the transfer of metal cation across the interface between two immiscible electrolyte solutions facilitated by complex formation with a ligand at the interface was investigated both theoretically and experimentally.