Journal ArticleDOI
Organic syntheses by means of noble metal compounds-XLVIII : Carbonylation of butadiene catalyzed by palladium-phosphine complexes
Jiro Tsuji,Y. Mori,M. Hara +2 more
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TLDR
In the presence of halide, one mole of butadiene reacts with one moles of carbon monoxide to give the 3,8-nonadienoate as discussed by the authors.About:
This article is published in Tetrahedron.The article was published on 1972-01-01. It has received 50 citations till now. The article focuses on the topics: Carbonylation & Palladium.read more
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Book ChapterDOI
57 – Organopalladium Compounds in Organic Synthesis and in Catalysis
B.M. Trost,T.R. Verhoeven +1 more
Journal ArticleDOI
Telomerization: Advances and Applications of a Versatile Reaction
TL;DR: An overview of the versatility of telomerization is given based on examples from research and industry, particular emphasis is placed on catalyst and process development as well as mechanistic aspects.
Journal ArticleDOI
Selective palladium-catalyzed aminocarbonylation of 1,3-dienes: atom-efficient synthesis of β,γ-unsaturated amides.
TL;DR: The first palladium-based catalyst system for the aminocarbonylation of 1,3-dienes is described, which provides straightforward access to a variety of β,γ-unsaturated amides in good to excellent yields, often with high selectivities.
References
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Journal ArticleDOI
Organic Syntheses by Means of Noble Metal Compounds. VIII.1 Catalytic Carbonylation of Allylic Compounds with Palladium Chloride
Journal ArticleDOI
Organic syntheses by means of noble metal compounds—XLVII : Reaction of butadiene with aldehydes and ketones catalyzed by palladium-phosphine complexes
TL;DR: Palladium catalyzed reaction of butadiene with carbonyl compounds yields 1-substituted 2-vinyl-4, 6-heptadien-1-ols or 2-substantituted 3,6-divinyltetrahydropyrans Four stereoisomeric pyrans were characterized by NMR analysis as discussed by the authors.
Journal ArticleDOI
The Dimerization of Butadiene in Methanol by a Palladium Complex Catalyst
Journal ArticleDOI
Organic syntheses by means of noble metal compounds—XLVI : Catalytic carbonylation of conjugated dienes
S. Hosaka,J. Tsuji +1 more
TL;DR: Palladium catalysed carbonylation in alcohol of butadiene, isoprene, piperylene and chloroprene has been studied in this paper, and 4-methyl-3-pentenoate was obtained with high selectivity.