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Journal ArticleDOI

Organophotoredox-Catalyzed Direct C–H Amination of 2H-Indazoles with Amines

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TLDR
A mechanistic study revealed that a single electron transfer pathway might be involved in this reaction, and this protocol is used for free aminated 2H-indazole synthesis.
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This article is published in Organic Letters.The article was published on 2020-06-24. It has received 56 citations till now. The article focuses on the topics: Amination.

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Citations
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Photoredox-Catalyzed C-H Functionalization Reactions.

TL;DR: The use of photoredox catalysis in C-H functionalization reactions has garnered enormous interest and utility in the past several decades as discussed by the authors, including natural product synthesis, drug discovery, radiolabeling, bioconjugation, materials, and fine chemical synthesis.
Journal ArticleDOI

Recent advances of visible-light photocatalysis in the functionalization of organic compounds

TL;DR: In this paper , a critical assessment of the current literature on visible-light photocatalysis is presented, pointing out the recent developments and potential applications in the field of photochemical research.
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Visible-light-induced silylation: an update

TL;DR: In this article, the authors summarized the recent findings and developments in the emerging area of photocatalytic silylation with literature coverage mainly extending from 2014 to February 2021, mainly focusing on visible-light-driven functionalization of various organic systems.
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Light-induced borylation: developments and mechanistic insights

TL;DR: In this paper, the authors have discussed all the UV-and visible-light-induced borylation strategies developed in the last decade, and special attention is given to the mechanisms of these bORYlation methodologies for better understanding of reaction insights.
References
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Journal ArticleDOI

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

TL;DR: The conversion of these bench stable, benign catalysts to redox-active species upon irradiation with simple household lightbulbs represents a remarkably chemoselective trigger to induce unique and valuable catalytic processes.
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Visible light photoredox catalysis: applications in organic synthesis

TL;DR: This tutorial review provides a historical overview of visible light photoredox catalysis in organic synthesis along with recent examples which underscore its vast potential to initiate organic transformations.
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Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides.

TL;DR: The conceptual basis and utility of the latest, "fourth-generation" palladium catalyst for the coupling of amines and related reagents with aryl halides is described and the effects of electronic properties on C-C and C-N bond-forming reductive elimination are similar.
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Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications

TL;DR: This Review comprehensively highlights recent advances in intra- and intermolecular C-H amination reactions utilizing late transition metal-based catalysts using mechanistic scaffolds and types of reactions.
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Visible light photoredox-controlled reactions of N-radicals and radical ions

TL;DR: This tutorial review highlights recent advances in this rapidly developing area with particular emphases put on the working models and new reaction design in visible light photoredox catalysis.
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