Journal ArticleDOI
Palladium(II)-Catalyzed Dehydrogenative Strategy for Direct and Regioselective Oligomerization of BODIPY Dyes.
Zhengxin Kang,Fan Lv,Qinghua Wu,Heng Li,Zhongxin Li,Feng-xi Wu,Zhaoyun Wang,Lijuan Jiao,Erhong Hao +8 more
TLDR
In this article, a family of directly β,γ-linked BODIPY oligomers up to pentamers were regioselectively prepared via Pd(II)-catalyzed oxidative C-H cross-coupling.About:
This article is published in Organic Letters.The article was published on 2021-10-04. It has received 5 citations till now. The article focuses on the topics: BODIPY & Intersystem crossing.read more
Citations
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Journal ArticleDOI
Development of Geometry-Controlled All-Orthogonal BODIPY Trimers for Photodynamic Therapy and Phototheragnosis
Alejandro Prieto-Castañeda,Fernando García-Garrido,Carolina Díaz-Norambuena,Blanca Escriche-Navarro,Alba García-Fernández,Jorge Bañuelos,Esther Rebollar,Inmaculada García-Moreno,R. Martínez‐Máñez,S. de la Moya,Antonia R. Agarrabeitia,Maria J. Ortiz +11 more
TL;DR: An easy synthetic protocol for selectively developing all-orthogonal BODIPY trimers with unprecedented geometries on the basis of selecting methyl oxidation versus electrophilic formylation of key dimeric precursors is established.
Journal ArticleDOI
Chemodivergent Synthesis of Indeno[1,2-b]indoles and Isoindolo[2,1-a]indoles via Mn(III)-Mediated or Electrochemical Intramolecular Radical Cross-Dehydrogenative Coupling.
TL;DR: Plausible mechanisms of the chemodivergent reactions were proposed and Mn(OAc)3·2H2O selectively promoted an intramolecular radical C-H/C-H dehydrogenative coupling reaction to provide indeno[1,2-b]indole and isoindolo[2,1-a]indoles.
Journal ArticleDOI
Copper-catalyzed α-selective cross-dehydrogenative coupling of BODIPY dyes with aldehydes: A new route to acylated BODIPYs and dipyrromethenes
TL;DR: In this paper , a copper-catalyzed direct acylation of BODIPYs with aldehydes via C-H bond activation was developed, in which acyl radicals were formed from aldehyde in the presence of TBHP as radical initiator, and selectively reacted with BODYs at the α-positions.
Journal ArticleDOI
Regioselective Synthesis of Directly Connected BODIPY Dimers through Oxidative Coupling of α-Amino-Substituted BODIPYs.
Long Wang,Qinghua Wu,Zhengxin Kang,Xing Guo,Wei Miao,Zhongxin Li,Huiquan Zuo,Hua Wang,Hongwei Si,Lijuan Jiao,Erhong Hao +10 more
TL;DR: In this paper , a family of directly β,β-linked BODIPY dimers with amino groups at α-positions were regioselectively prepared by the oxidative coupling reaction of α-amino-substituted BODYs.
References
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Journal ArticleDOI
BODIPY dyes and their derivatives: syntheses and spectroscopic properties.
Aurore Loudet,Kevin Burgess +1 more
Journal ArticleDOI
Structural modification strategies for the rational design of red/NIR region BODIPYs
TL;DR: This review focuses on classifying different types of long wavelength absorbing BODIPY dyes based on the wide range of structural modification methods that have been adopted, and on tabulating their spectral and photophysical properties.
Journal ArticleDOI
Oxidative C-H/C-H Coupling Reactions between Two (Hetero)arenes.
TL;DR: This review provides a comprehensive overview of the fundamentals and applications of transition metal-mediated/catalyzed oxidative C-H/C-H coupling reactions between two (hetero)arenes.
Journal ArticleDOI
Designing excited states: theory-guided access to efficient photosensitizers for photodynamic action.
Yusuf Cakmak,Safacan Kolemen,Selin Duman,Yavuz Dede,Yusuf Dolen,Bilal Kilic,Ziya Köstereli,Leyla Tatar Yıldırım,A. Lale Doğan,Dicle Guc,Engin U. Akkaya +10 more
TL;DR: This work mainly employed a popular variant of MCSCF techniques; the complete active space SCF (CASSCF) method in combination with relatively large basis sets and different active spaces, capable of providing a conceptually complete picture of the photophysics taking place.
Journal ArticleDOI
Reaction-based BODIPY probes for selective bio-imaging
Safacan Kolemen,Engin U. Akkaya +1 more
TL;DR: 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) based chemodosimeters are highlighted which have been used to image bio-thiols, reactive oxygen/nitrogen species, and gaseous molecules in living cells.