Journal ArticleDOI
Performance of polymer electrolyte cells at +25 to +100°C
M.Z.A. Munshi,Boone B. Owens +1 more
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In this article, solid state rechargeable polymer electrolyte batteries utilizing lithium anodes and V6O13 composite cathodes were investigated at 100°C and over a hundred cycles were obtained at the C/5 rate (45% depth of discharge) with greater than 75% of the initial capacity of V6 O13 being maintained at cycle number one hundred.About:
This article is published in Solid State Ionics.The article was published on 1988-01-01. It has received 58 citations till now. The article focuses on the topics: Propylene carbonate & Lithium.read more
Citations
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Modeling of Galvanostatic Charge and Discharge of the Lithium/Polymer/Insertion Cell
TL;DR: In this article, the galvanostatic charge and discharge of a lithium anode/solid polymer separator/insertion cathode cell is modeled using concentrated solution theory, which is general enough to include a wide range of polymeric separator materials, lithium salts, and composite insertion cathodes.
Journal ArticleDOI
The history of polymer electrolytes
TL;DR: A brief survey of the conductive complexes formed between solvating molecules and metal salts is given in this article, where the elucidation of the special conduction mechanism of these materials have been a challenging emulation for the scientific community.
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Ionic conductivity of plasticized(PEO)-LiCF3SO3 electrolytes
TL;DR: In this article, the ionic conductivity has been determined for a (PEO)9LiCF3SO3 polymer electrolyte with added plasticizers, and the results showed that adding 50% of the plasticizers by mol. weight of PEO to the (pEO) 9LiCF 3SO3 complex yielded mechanically stable films with an ionicconductivity of 9.0×10−4
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Review of hybrid polymer electrolytes and rechargeable lithium batteries
TL;DR: The electrochemical and ion transport properties of heterogeneous electrolyte mixtures are reviewed in this paper, restricted to lithium ion conducting electrolytes and to electrolytes containing at least one polymer component.
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Role of plasticizer's dielectric constant on conductivity modification of PEO–NH4F polymer electrolytes
Manoj Kumar,Satpal Singh Sekhon +1 more
TL;DR: In this paper, the authors found that the plasticization of polyethylene oxide (PEO)-ammonium fluoride (NH4F) polymer electrolytes has an increase in conductivity value and the magnitude of increase has been found to depend upon the dielectric constant of the plasticizer used.
References
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Complexes of alkali metal ions with poly (ethylene oxide)
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Phase Diagrams and Conductivity Characterization of Some PEO ‐ LiX Electrolytes
C. D. Robitaille,D. Fauteux +1 more
TL;DR: In this paper, the activation energy of ion transport is independent of the anion, and remains mainly constant at 0.7 eV over the concentration range studied for the ion pair formation.
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Influence of ion pairing on cation transport in the polymer electrolytes formed by poly(ethylene oxide) with sodium tetrafluoroborate and sodium tetrahydroborate
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Assessment of polymer-electrolyte batteries for EV and ambient temperature applications
Michel Gauthier,Denis Fauteux,G. Vassort,Andre Belanger,Michel Duval,P. Ricoux,J. ‐M. Chabagno,D. Muller,P. Rigaud,Michel Armand,D. Deroo +10 more
TL;DR: In this article, the feasibility of polyether-based all-solid-state cells has been assessed in a joint research and development program and polyether electrolytes have been found that allow room temperature (26/sup 0/C) operation at 3-20 µ..A/cm/sup 2/