Journal ArticleDOI
Photo-induced cyclodimerization of electron-rich aromatic olefins in the presence of transition metal complexes
TLDR
In this article, an acetonitrile solution of phenyl vinyl ether in the presence of various metal complexes[Fe(III) and Mn(II) complexes] gave two cyclodimers.Abstract:
Irradiation of an acetonitrile solution of phenyl vinyl ether in the presence of various metal complexes[Fe(III) and Mn(II) complexes] gave two cyclodimers. Similar irradiation of 1,1-dimethylindene and 1,1-diphenylethylene afforded the corresponding cyclodimers. In these photodimerization, the metal complexes with ligands such as 2,2′-bipyridine and 1,10-phenanthroline served as catalysts for electron-transfer reaction.read more
Citations
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Journal ArticleDOI
Critical review and perspective of macromolecularly imprinted polymers.
TL;DR: This paper reviews the main approaches employed, highlights studies of interest with an emphasis on recent work, and offers suggestions for future success in the field of macromolecularly imprinted polymers.
Book ChapterDOI
Homoleptic Complexes of 2,2′-Bipyridine
TL;DR: The homoleptic 2,2'-bipyridine (bpy) ligand is a strong field ligand that forms relatively stable complexes, with the inherent M-N bond strength enhanced by the chelate effect as mentioned in this paper.
Journal ArticleDOI
Attempts to Fill the Gap Between Enzymatic, Homogeneous, and Heterogeneous Catalysis
TL;DR: In this paper, a rational design of solid heterogeneous catalysts is proposed to improve reaction rate and selectivity by increasing the concentration and activation of reactants in the vicinity of the active sites, and stabilizing transition states or intermediate products.
Book ChapterDOI
The Chemistry of Excited Complexes: a Survey of Reactions
TL;DR: In this article, the authors focus on the chemistry of excited complexes and the maximum rate for the process is determined by the rate constant for diffusion control in the solvent employed, which is a function of the number of collisions that must occur within the lifetime of the excited state.
Journal ArticleDOI
L-histidine imprinted synthetic receptor for biochromatography applications.
TL;DR: These histidine imprinted beads can be used several times without considerable loss of cyt c adsorption capacity and used for cyt c and ribonuclease A (surface histidine exposed proteins) and enantiometric separation of D- and L-histidine by FPLC.
References
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Journal ArticleDOI
Radical ions in photochemistry. I. 1,1-Diphenylethylene cation radical
R. A. Neunteufel,D. R. Arnold +1 more
Journal ArticleDOI
Photoreactions of N -Vinylcarbazole Induced by Metal Salts. VI. Cyclodimerization Catalyzed by Copper(II) Perchlorate in Aprotic Solvents
TL;DR: In this paper, the photocyclodimerization of N-vinyl carbazole (VCZ) catalyzed by Cu(ClO4)2·6H2O(Cu(II)) in tetrahydrofuran was investigated under irradiation at 365 nm.