Journal ArticleDOI
Photochemistry of an ozone molecular complex with iodine monochloride in cryogenic matrixes. The infrared spectra of iodosyl chloride (OICl) and iodyl chloride (O2ICl)
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In this article, the authors describe the formation of complexes moleculaires O 3 •ICl par codeposition of O 3 and ICl dans des matrices d'Ar, Kr et N 2.Abstract:
Formation de complexes moleculaires O 3 •ICl par codeposition de O 3 et ICl dans des matrices d'Ar, Kr et N 2 . Par irradiation a 470-750 nm photodissociation tres sensible de ces complexes en chlorure de iodosyle OICl, dont la decomposition prolongee conduit a des atomes O et au chlorure d'iodyle O 2 ICl. Decomposition de ces chlorures sous rayonnement UV a 240-320 nmread more
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Tetrahedrane and Cyclobutadiene
TL;DR: The tetrahedranes must necessarily include the corresponding cyclobutadienes, and it was found appropriate to organize the article at the same time as a final account of the cyclobubutadiene problem.
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Reactions of Ground State and Electronically Excited Atoms of Main Group Elements: a Matrix Perspective
TL;DR: Comparison between Gas-Phase and Matrix Isolation Studies 4210 and Reaction Pathways 4202 A. Simple Addition Reactions 4204 B. Insertion 4205 C. Isomerization 4207 D. Decomposition 4208 IV.
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Tetrahedran und Cyclobutadien
TL;DR: In this article, a provozierende Frage wird im ersten Teil des vorliegenden Forschrittsberichts versucht.
Journal ArticleDOI
Main group coordination chemistry at low temperatures: A review of matrix isolated Group 12 to Group 18 complexes
TL;DR: The available data on main group (Groups 12-18) Lewis acid base, donor-acceptor, charge transfer and van der Waals complexes stabilised by matrix isolation techniques are presented, tabulated and evaluated in conjunction with data from complementary gas phase experiments and computational chemistry as discussed by the authors.
Journal ArticleDOI
Selective Monooxidation of Light Alkanes Using Chloride and Iodate
George C. Fortman,Nicholas C. Boaz,Dominik Munz,Michael M. Konnick,Roy A. Periana,John T. Groves,T. Brent Gunnoe +6 more
TL;DR: An efficient system for the direct partial oxidation of methane, ethane, and propane using iodate salts with catalytic amounts of chloride in protic solvents is described.