Journal ArticleDOI
Poly(vinylsaccharide)s, 5. Synthesis and characterization of poly(vinylsaccharide)s of the amide type with disaccharides in the side chain
Joachim Klein,Alireza Haji Begli +1 more
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TLDR
In this paper, the synthesis of well-defined monovinylsaccharide monomers containing disaccharide units was described and the influence of the structural differences of the disarachide units on the solution properties was studied by viscosity and light scattering measurements.Abstract:
The synthesis of well-defined monovinylsaccharide monomers containing disaccharide units is described. Four different monomers, N-disaccharide-substituted acryl- and methacrylamides, were prepared and polymerized to the corresponding polymers by free-radical polymerization in aqueous solution using different initiator systems. The influence of the structural differences of the disaccharide units on the solution properties was studied by viscosity and light scattering measurements. A comparison with known poly(vinylsaccharide)s with monosaccharides in the side chain is made.read more
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Comb-like and block liquid crystalline polymers for biological applications
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Synthetic polymers functionalized by carbohydrates: a review
TL;DR: In this article, the authors present a review of methods of anchoring carbohydrates onto polymers and the advantages and disadvantages associated with each method, their current and potential applications, and their characterization methods.
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Protection and Polymerization of Functional Monomers. 30. Anionic Living Polymerization of 4-Alkylstyrenes Containing Acetal-Protected Monosaccharide Residues
Surapich Loykulnant,Akira Hirao +1 more
TL;DR: In this article, three para-substituted styrene derivatives, p-[3-(1,2:5,6-di-O-isopropylidene-α-d-glucofuranose-3-oxy)propyl]styrene (1), p-[1, 2:3,4,5,4]-iO-Isopropylonidene (α,d-galactopyranose 6-oxy)-propyl], and p-[11-(1.2: 5,6)-di
Journal ArticleDOI
Protection and Polymerization of Functional Monomers. 28. Anionic Living Polymerization of Styrene Derivatives Containing Acetal-Protected Monosaccharide Residues
TL;DR: In this paper, six styrene derivatives meta-substituted with acetal-protected glucofuranoses were synthesized by the Williamson reactions of m- or p-(chloromethyl)styrene with the corresponding protected monosaccharides in DMF and were anionically polymerized.
Journal ArticleDOI
Chemo-Enzymatic Synthesis of a Glycopolymer Carrying Clustered-N-ACETYL-β-lactosamine Moieties
TL;DR: A polyacrylamide derivative having a β-linked N-acetyllactosamine moiety, a major component of oligosaccharide chains of glycoproteins, on each repeating unit was synthesized via a chemo-enzymatic process as discussed by the authors.
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