Synthese stereoselective de dihydro-3,6 isopropyl-6 pyrannecarboxylates-2 de methyle a partir d'isopropyl-5 vinyl-6 dioxanne-1,4ones-2

Polysubstituted dihydropyrans via the enolate Claisen rearrangement. A stereocontrolled route to C-pyranosides

Claisen rearrangement over the past nine decades.

Recent developments in the synthesis of C-glycosides

Strategy and methodology development for the total synthesis of polyether ionophore antibiotics.

This article surveys variants of the Claisen rearrangement that are of general use in stereoselective organic synthesis. Recent results concerning the influence of steric and electronic parameters on transition state geometries are highlighted. The impact of the Claisen methodology in modern synthetic strategy and its application for the preparation of highly functionalized derivatives is exemplified.

Polysubstituted dihydropyrans via the enolate Claisen rearrangement. A stereocontrolled route to C-pyranosides

Citations

Claisen rearrangement over the past nine decades.

Recent developments in the synthesis of C-glycosides

Strategy and methodology development for the total synthesis of polyether ionophore antibiotics.

7.2 – Claisen Rearrangements

Synthesis of a C(22)−C(34) Halichondrin B Precursor via Ring Opening−Double Ring Closing Metathesis

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