Journal ArticleDOI
Preparation and Reactions of Unsymmetrically Labeled Hydroperoxides: Solvent Viscosity Dependent Oxygen Scrambling of Cumylperoxyl Free Radicals
Sarah E. Caldwell,Ned A. Porter +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1995-08-01. It has received 10 citations till now. The article focuses on the topics: Radical & Viscosity.read more
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Journal ArticleDOI
Free radical oxidation of polyunsaturated lipids: New mechanistic insights and the development of peroxyl radical clocks.
TL;DR: The current understanding of the mechanism of unsaturated lipid peroxidation is presented, effectively updating the Account on the same topic published 25 years ago, and a powerful peroxyl radical clock methodology is developed, which can be used to determine rate constants for reactions ofperoxyl radicals with molecules having rate constants ranging from 1 to 10 M(-1) s(-1).
Journal ArticleDOI
Chemistry of beta-(Acyloxy)alkyl and beta-(Phosphatoxy)alkyl Radicals and Related Species: Radical and Radical Ionic Migrations and Fragmentations of Carbonminus signOxygen Bonds.
Journal ArticleDOI
A Perspective on Free Radical Autoxidation: The Physical Organic Chemistry of Polyunsaturated Fatty Acid and Sterol Peroxidation
TL;DR: A physical organic approach to the problem of free radicals in biology and medicine is highlighted in this Perspective with stereochemical, kinetic, and extrathermodynamic probes applied to the study of mechanism.
Journal ArticleDOI
Oxidation of alkanes by iodosylbenzene (PhIO) catalysed by supported Mn(III) porphyrins : Activity and mechanism
TL;DR: In this paper, the effects of reaction solvent, catalyst support and dioxygen on the oxidation yields and product distributions of pentane and cyclohexane with iodosylbenzene have been studied.
Journal ArticleDOI
The oxidation of ethylbenzene and other alkylaromatics by dioxygen catalysed by iron(III) tetrakis(pentafluorophenyl)porphyrin and related iron porphyrins
TL;DR: In this article, a free radical autoxidation mechanism was proposed for the degradation of the porphyrin ligand with 1-phenylethoxyl, acetophenone, and 1-phylperoxyl radicals.
Related Papers (5)
Solvent Effects in the Reactions of Free Radicals and Atoms. IX. Effect of Solvent Polarity on the Reactions of Peroxy Radicals
Dale G. Hendry,Glen A. Russell +1 more
The role of hydroperoxides in photo-oxidative degradation of cis-1,4-polybutadiene
Darwish Lala,Jan F. Rabek +1 more