Journal ArticleDOI
Preparation, characterization and cyclic voltammetric behaviour of dimeric sulphidomolybdenum(V) dithiocarbamate complexes
K.S. Nagaraja,M.R. Udupa +1 more
TLDR
Mo 2 S 4 (R 2 dtc) 2 (R = methyl, ethyl or benzyl; R 2 = pyrrolidinyl, piperidinyl or 4-morpholinyl) have been prepared starting from ammonAbout:
This article is published in Polyhedron.The article was published on 1985-01-01. It has received 5 citations till now. The article focuses on the topics: Dithiocarbamate & Cyclic voltammetry.read more
Citations
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Journal ArticleDOI
Synthesis, Spectroscopic Characterization, and Structural Studies of Bis(m-sulfido)bis[{O,O-dialkyl (alkylene) dithiophosphato}oxomolybdenum(V)] Complexes. Crystal Structures of Mo(2)O(2)S(2)[S(2)P(OEt)(2)](2), Mo(2)O(2)S(2)[S(2)P(OEt)(2)](2).2NC(5)H(5), and Mo(2)O(3)[S(2)P(OPh)(2)](4).
TL;DR: In this article, a series of new complexes, Mo2O2S2[S2P(OR)2]2 (where R = Et, n-Pr, i-Pr) were obtained by dropwise addition of an ethanolic solution of the ammonium or sodium salt of the appropriate O,O-dialkyl or -alkylene dithiophosphoric acid, or the acid itself, to a hot aqueous solution of molybdenum(V) pentachloride.
Journal ArticleDOI
Synthesis, reactivity and redox properties of dinuclear molybdenum-sulfur complexes
C. Coyle Lee,Thomas R. Halbert,Wie Hin Pan,Mark Andrew Harmer,L. Wei,M.E. Leonowicz,C.O.B. Dim,Kenneth F. Miller,Alice E. Bruce,Stephen Mckenna,James L. Corbin,Scot Wherland,Edward I. Stiefel +12 more
TL;DR: In this paper, the synthesis of dinuclear Mo(V) complexes containing the Mo2S42+ core was reported, where the disulfido bridge was replaced by a bis-sulfido bridging.
Journal ArticleDOI
The designed synthesis and characterization of two novel heterometallic trinuclear incomplete cubane-like clusters [(CH3CH2)4N]{(M2CuS4)}(S2C2H4)2(PPh3) (M = Mo, W)
TL;DR: In this paper, two novel heterometallic trinuclear incomplete cubane-like clusters were synthesized by reaction of [(CH 3 CH 2 ) 4 N] 2 [M 2 S 4 (edt) 2 ] (M = Mo, W) with Cu(PPh 3 ) 2 (dtp) [where edt is 1,2-ethane-dithiolato ligand, dtp is S 2 P(OCH 2 CH 3 )2 − ].
Journal ArticleDOI
Reactivity of the tetrathiomolybdate(VI) anion towards hard and soft base chelating agents
TL;DR: In this paper, the authors investigated the interaction of hard base chelating agents (LH), such as 8-quinolinol (oxH), salicylaldehyde (salH), and N-nitrosophenylhydroxylamine (NphaH) with ammonium tetrathiomolybdate(VI) in aqueous solution yields disulphidomolybdenum(VI), and the ir absorptions at 540 and 510 cm−1 are assigned tov(Mo-S), which indicate that the two sulphido-groups
Journal ArticleDOI
Sulphidomolybdenum(V) complexes with amino acid dithiocarbamates
TL;DR: In this article, the interaction of ammonium tetrathiomolybdate with the barium salts of the dithiocarbamates (dtc) of glycine, DL-alanine and DL-2-aminobutyric acid yielded Ba[Mo2S4(dtc)]2.
References
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Journal ArticleDOI
Dialkyldithiocarbamate complexes of molybdenum(V) and molybdenum(VI)
Fred W. Moore,Melvin L. Larson +1 more
Journal ArticleDOI
Synthesis and electrochemistry of oxo- and sulfido-bridged molybdenum(V) complexes with 1,1-dithiolate ligands
Franklin A. Schultz,Virginia R. Ott,Debra S. Rolison,Dudley C. Bravard,John W. McDonald,William E. Newton +5 more
Journal ArticleDOI
Mo2S42+ core: new syntheses, new complexes, and electrochemical diversity
Journal ArticleDOI
On the preparation of binuclear S, S bridged molybdenum(V) complexes crystal and molecular structure of [Mo2S4(Et2dtc)2]
TL;DR: In this article, the X-ray crystal structure of MoO2S22+ has been determined and the MoMo distance of the diamagnetic compound is 2.817(2) A and the average Mo=St distance 2.099(4) A.