Pyrolysis of benzophenone oxime carbonates: a potential route to aryl imino ethers (aryl imidates)
TLDR
Aryl ketoxime carbonates have been found to undergo decompositions at temperatures ranging from 180-200°C to give carbon dioxide and aryl imino ethers (imidates) as discussed by the authors.Abstract:
Aryl ketoxime carbonates have been found to undergo decompositions at temperatures ranging from 180–200°C to give carbon dioxide and aryl imino ethers (imidates). This pyrolysis could prove to be a...read more
Citations
More filters
Book ChapterDOI
Synthesis of Iminium Salts, Orthoesters and Related Compounds
TL;DR: In this article, the authors deal with activated amides, i.e. salt-like compounds, imino derivatives of carboxylic acids as well as compounds which formally arise by complete esterification or amidation of car boxylic orthoacids.
Journal ArticleDOI
An all-purpose preparation of oxime carbonates and resultant insights into the chemistry of alkoxycarbonyloxyl radicals
TL;DR: In this article, oxime carbonates have been synthesised and their potential studied as a new class of radical precursor, and a general synthetic route, avoiding laboratory use of phosgene, was developed Alkyl or aryl 1H-imidazole-1-carboxylates were prepared from the corresponding alcohols and 1,1-carbonyldiimidiazole, then reacted with oximes in the presence of base UV photolyses of oximecarbonates released particular N- and O-centred radicals suitable for spect
Journal ArticleDOI
A mild, expedient, one-pot trifluoromethanesulfonic anhydride mediated synthesis of N-arylimidates
TL;DR: In this paper, the direct transformation of various secondary amides into N-arylimidates via mild electrophilic amide activation with trifluoromethanesulfonic anhydride (Tf2O) in the presence of 2-chloropyridine (2-ClPyr) is described.
Book ChapterDOI
Pyrolysis of Other Nitrogen-Containing Compounds
TL;DR: In this article, the pyrolysis of nitro and nitroso compounds is presented, among which, the most common ones are nitromethanes, various other nitroalkanes, nitrobenzene, and several nitro derivatives of heterocycles.
Journal ArticleDOI
A copper-catalyzed reaction of oximes with diisopropyl azodicarboxylate: an alternative method for the synthesis of oxime carbonates.
TL;DR: A new Cu-catalyzed efficient protocol is described for the transformation of oximes to the corresponding carbonate derivatives, providing a synthetically useful process, which tolerates a wide range of functional groups.