Journal ArticleDOI
Reaction de metathese des olefines induite photochimiquement en presence d'un complexe de metal de transition : VI. Existence probable d'un metallodichlorocarbene primaire
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TLDR
In this paper, a mechanism for the formation of these compounds is outlined, and the mechanism for their formation is described in terms of the insertion of metalladichlorocarbene moieties into the carbon double bond.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1980-02-19. It has received 35 citations till now. The article focuses on the topics: Enol & Double bond.read more
Citations
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Book ChapterDOI
Polymerization of Mono- and Di-substituted Acetylenes
TL;DR: Substituted polyacetylenes (polyalkynes) are a relatively old class of polymers, which have been widely investigated and reviewed, particularly in the last decade.
Journal ArticleDOI
Metathesis Polymerization of Substituted Acetylenes and Norbornene by M(CO) 6 -Ph 2 CCl 2 -hν (M=Mo, W) Catalysts
TL;DR: Metathesis Polymerization of Substituted Acetylenes and Norbornene by M(CO) 6 -Ph 2 CCl 2 -hν (M=Mo, W) Catalysts as mentioned in this paper.
Book ChapterDOI
Computer Aids for Organometallic Chemistry and Catalysis
TL;DR: In this article, the authors describe the flowchart of the transition metal discovery process (TAMREAC), placing stress specifically on the matter of interest for the chemist, namely, basic reaction steps.
Journal ArticleDOI
Polymerization of o -Trimethylsilylphenylacetylene Initiated by a Tungsten Carbene Complex
TL;DR: In this article, the polymerization of o-trimethylsilylphenylacetylene (o-Me3SiPA) initiated by tungsten carbene complex (I) was investigated under various conditions.
Journal ArticleDOI
The first example of tungsten-based carbene generation from WCl6 and atomic carbon and its use in olefin metathesis
TL;DR: In this paper, a new route for the synthesis of tungsten-based carbenes generated by the reaction of WCl 6 with atomic carbon in a carbon arc reactor was described.
References
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Journal ArticleDOI
Photochemically induced olefin metathesis by transition metal complex. I. Intermediacy of pentacarbonylchlorotungsten
Journal ArticleDOI
Possible role of hydrido-metal complexes in metathesis, isomerization, dimerization, and polymerization of alkenes
Journal ArticleDOI
Mechanism of the olefin metathesis reaction. 4. Catalyst precursors in tungsten(VI) based systems
Journal ArticleDOI
Reaction de metathese des olefines induite photochimiquement en presence d'un complexe de metal de transition
TL;DR: The photo-induced metathesis of cis and trans-RCH=CHMe gives 2-butene in a very high trans but low cis stereoselectivity as mentioned in this paper.
Related Papers (5)
Hexacarbonyltungsten and carbon tetrachloride as a photochemical system for olefin metathesis
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