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Open AccessJournal ArticleDOI

Reaction invariants and their importance in the analysis of eigenvectors, state observability and controllability of the continuous stirred tank reactor

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TLDR
In this article, two different projection operators are found, projecting the state space of a continuous stirred tank reactor (C.S.T.R.) dynamic model on the space of asymptotically invariant states and on the true invariant state for a batch reactor.
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This article is published in Chemical Engineering Science.The article was published on 1974-09-01 and is currently open access. It has received 68 citations till now. The article focuses on the topics: Observability & Controllability.

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Citations
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Journal ArticleDOI

Thermodynamics and chemical systems stability: The CSTR case study revisited

TL;DR: In this article, the stability analysis of the Continuous Stirred Tank Reactor (CSTR) model by considering thermodynamics-based arguments is considered, and different Lyapunov function candidates related to the thermodynamics, more specifically based on the entropy, the entropy production and the internal energy, are considered.
Journal ArticleDOI

On the use of extensive variables in process dynamics and control

TL;DR: In this paper, a novel approach is presented for the physical interpretation of the slow and fast modes of process dynamics and the synthesis of multivariable and nonlinear control structures by the use of extensive thermodynamic variables.
Book ChapterDOI

Dynamical modelling, analysis, monitoring and control design for nonlinear bioprocesses

TL;DR: A key feature of the paper is to show how to incorporate the well-known knowledge about the dynamics of biochemical processes in monitoring and control algorithms capable of dealing with the process uncertainty by introducing, for instance in the control algorithms, an adaptation scheme.
Journal ArticleDOI

Variant and invariant states for chemical reaction systems

TL;DR: A linear transformation is proposed that allows viewing a complex nonlinear chemical reaction system via decoupled dynamic variables, each one associated with a particular phenomenon such as a single chemical reaction, a specific mass transfer or heat transfer.
Journal ArticleDOI

Metodología para la Obtención de Modelos Semifísicos de Base Fenomenológica Aplicada a una Sulfitadora de Jugo de Caña de Azúcar

TL;DR: In this article, the Phenomenological Based Semi-physical Model (PBSM) is presented as a useful tool for the design, control and optimization of chemical and bio-technology processes.
References
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Journal ArticleDOI

Response modes of continuous stirred tank reactors

TL;DR: In this paper, it was shown that the fundamental stoichiometric constraints on a set of chemical reactions carry over to the dynamics of open systems in the analysis of asymptomatic stability.
Journal ArticleDOI

Reaction invariants in the control of continuous chemical reactors

TL;DR: In this paper, it was shown that a subset of the thermodynamic states remains invariant to both the chemical reactions and the control actions, and that the reduced reaction matrix and the mean residence time still determine the response modes entirely.
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