Journal ArticleDOI
Reactions of acyl anion equivalents derived from cyanohydrins, protected cyanohydrins and α-dialkylaminonitriles
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This article is published in Tetrahedron.The article was published on 1983-01-01. It has received 119 citations till now. The article focuses on the topics: Reactivity (chemistry) & Addition reaction.read more
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Some recent applications of α-amino nitrile chemistry
Dieter Enders,John P. Shilvock +1 more
TL;DR: A review of α-amino nitriles can be found in this paper, where the authors highlight recent developments in the chemistry and applications of αamino n-nitriles.
Journal ArticleDOI
Unsaturated nitriles: conjugate additions of carbon nucleophiles to a recalcitrant class of acceptors.
Fraser F. Fleming,Qunzhao Wang +1 more
Journal ArticleDOI
Catalytic Conjugate Additions of Carbonyl Anions under Neutral Aqueous Conditions
TL;DR: The conjugate addition of carbonyl anions catalyzed by thiazolium salts that is fully operative under neutral aqueous conditions has been accomplished and the scope of the reaction has been examined and found to accommodate various alpha-keto carboxylates and beta-aryl substituted unsaturated 2-acyl imidazoles.
Journal ArticleDOI
Regioselectivity of the Reactions of Heteroatom-Stabilized Allyl Anions with Electrophiles.
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Heterocycles from α-aminonitriles.
Nicola Otto,Till Opatz +1 more
TL;DR: This article focuses on synthetic methodologies using α-aminonitriles using their bifunctional nature which is the basis of their reactivity as α-amino carbanions and as iminium ions.
References
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Journal ArticleDOI
Synthetic applications of trimethylsilyl cyanide. Efficient synthesis of .beta.-aminomethyl alcohols
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New horizons in carbonyl chemistry: reagents for nucleophilic acylation
Journal ArticleDOI
Anions of protected cyanohydrins as acyl carbanion equivalents and their use in a new synthesis of ketones
Gilbert Stork,Luis Maldonado +1 more