Journal ArticleDOI
Recent advances in S-functionalized N-heterocyclic carbene ligands: From the synthesis of azolium salts and metal complexes to applications
TLDR
In this paper, a review summarizes the recent progress in the field of S-functionalized N-heterocyclic carbene ligands and their metal complexes and discusses the syntheses of the azolium precursors and of the corresponding metal complexes as a function of five different S-containing chemical groups examined here: thiolate, thioether, thiophene, sulfonate and thione.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 2014-02-01. It has received 88 citations till now. The article focuses on the topics: Homogeneous catalysis & Carbene.read more
Citations
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Journal ArticleDOI
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes.
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Smart N-Heterocyclic Carbene Ligands in Catalysis
TL;DR: This review is to comprehensively describe all types of smart NHC ligands by focusing attention on the catalytically relevant ligand-based reactivity.
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N-Heterocyclic Carbene Complexes of Copper, Nickel, and Cobalt
TL;DR: The emergence of N-heterocyclic carbenes as ligands across the Periodic Table had an impact on various aspects of the coordination, organometallic, and catalytic chemistry of the 3d metals, both from the fundamental viewpoint but also in applications.
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Metal complexes with oxygen-functionalized NHC ligands: synthesis and applications
TL;DR: This review aims at providing a comprehensive update on a specific class of ligands at the intersection between the two categories of hybrid NHC ligands in which the functionality associated with the carbene donor is of the oxygen-donor type.
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Recent Advances on Computational Investigations of N-Heterocyclic Carbene Catalyzed Cycloaddition/Annulation Reactions: Mechanism and Origin of Selectivities
TL;DR: The detailed mechanisms, role of NHC, and origin of chemo‐ and stereoselectivity of these kinds of reactions were illustrated to provide valuable insights for rational design of new NHC‐catalyzed cycloaddition/annulation reactions with high selectivities.
References
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A stable crystalline carbene
TL;DR: Synthese, structure et caracterisation du (1,3-bis [1-adamantyl]-2, 3-dihydro)-2,carbenoimidazole prepare par deprotonation du chlorure de (1 3-bis] [1]- imidazolium as discussed by the authors.
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N-heterocyclic carbenes: a new concept in organometallic catalysis.
TL;DR: N-Heterocyclic carbenes have become universal ligands in organometallic and inorganic coordination chemistry as mentioned in this paper, and they not only bind to any transition metal, be it in low or high oxidation states, but also to main group elements such as beryllium, sulfur, and iodine.
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N-Heterocyclic Carbenes in Late Transition Metal Catalysis
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Heterocyclic Carbenes: Synthesis and Coordination Chemistry
TL;DR: New methods for the synthesis of complexes with N-heterocyclic carbene ligands such as the oxidative addition or the metal atom template controlled cyclized isocyanides have been developed recently.
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N-Heterocyclic Carbenes†‡
TL;DR: The chemistry of N-heterocyclic carbenes has long been limited to metal coordination compounds derived from azolium precursors, a development that was started by Ofele and Wanzlick in 1968 as discussed by the authors.