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Journal ArticleDOI

Recent advances in the total synthesis of steroids via intramolecular cycloaddition reactions

Tetsuji Kametani, +1 more
- 01 Jan 1981 - 
- Vol. 37, Iss: 1, pp 3-16
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This article is published in Tetrahedron.The article was published on 1981-01-01. It has received 121 citations till now. The article focuses on the topics: Cycloaddition & Total synthesis.

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Cobalt‐Mediated [2 + 2 + 2]‐Cycloadditions: A Maturing Synthetic Strategy [New Synthetic Methods (43)]

TL;DR: Dicarbonyl (η5-cyclopentadienyl)cobalt functions as a matrix on which a variety of unsaturated organic substrates undergo mutual bond formation as mentioned in this paper.
Journal ArticleDOI

A Comprehensive History of Arynes in Natural Product Total Synthesis

TL;DR: All reports of total syntheses that utilize arynes in ways that build complexity or introduce motifs essential to the completion of their targets are recounted.
Journal ArticleDOI

Tandem [4+2]/[3+2] Cycloadditions of Nitroalkenes.

TL;DR: Denmark et al. as mentioned in this paper proposed a method to match the change in molecular complexity at each step with reactions of comparable synthetic complexity, which is a necessary condition for high synthetic efficiency.
Journal ArticleDOI

Sequentielle Transformationen in der Organischen Chemie eine Synthesestrategie mit Zukunft

TL;DR: The organisch-chemische Synthese hat stets eine grose Faszination auf den Chemiker ausgeubt, und sie wird auch in Zukunft nichts von ihrer Bedeutung verlieren as discussed by the authors.
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