Journal ArticleDOI
Rhodium-Catalyzed Asymmetric [4 + 2] Cycloisomerization Reactions
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This article is published in Journal of Organic Chemistry.The article was published on 1998-11-26. It has received 81 citations till now. The article focuses on the topics: Cycloisomerization & Rhodium.read more
Citations
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Transition-Metal-Catalyzed Reactions in Heterocyclic Synthesis
Journal ArticleDOI
Cycloisomerization of 1,n-enynes: challenging metal-catalyzed rearrangements and mechanistic insights.
TL;DR: This Review aims to highlight the main contributions in this field of catalysis and to propose and comment on the mechanistic insights of the recent discoveries.
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Modular Phospholane Ligands in Asymmetric Catalysis
TL;DR: This Account outlines the preparation and application of a class of phosphine ligands based upon the trans-2,5-disubstituted phospholane moiety and highlights the versatility of highly efficient bis(phospholane)rhodium catalysts that allow enantioselective hydrogenation to produce a diverse range of compounds containing C-N, C-O, and C-C stereogenic centers.
Journal ArticleDOI
Recent advances in enantioselective [2 + 2 + 2] cycloaddition
TL;DR: This short account discloses the recent results of inter- and intramolecular enantioselective cycloadditions of alkyne and/or alkene moiety using chiral transition metal catalysts.
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Cycloisomerisierungen von 1,n‐Eninen: faszinierende metallkatalysierte Umlagerungen und mechanistische Einblicke
TL;DR: In this paper, a Ubersicht will die wichtigsten Beitrage auf diesem Gebiet der Katalyse behandeln und die mechanistischen Erkenntnisse zu den neuesten Entdeckungen darlegen and kommentieren.
References
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Journal ArticleDOI
Transition Metal Catalyzed [5 + 2] Cycloadditions of Vinylcyclopropanes and Alkynes: A Homolog of the Diels-Alder Reaction for the Synthesis of Seven-Membered Rings
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Novel cyclization reactions on transition metal templates. The catalysis of intramolecular [4+2] cycloadditions by low-valent rhodium complexes
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Nickel-catalyzed intramolecular [4 + 4]-cycloadditions: a new method for the synthesis of polycycles containing eight-membered rings
Paul A. Wender,Nathan C. Ihle +1 more
Journal ArticleDOI
Nickel-catalyzed intramolecular [4+2] dienyne cycloadditions: an efficient new method for the synthesis of polycycles containing cyclohexa-1,4-dienes
Paul A. Wender,Thomas E. Jenkins +1 more
Journal ArticleDOI
On the asymmetric rh(I) catalyzed [4+2] cycloisomerization reaction. Electronic and torsional ligand control of absolute stereoselection.
Lydia McKinstry,Tom Livinghouse +1 more
TL;DR: The use of bisphosphine ligands related to DIOP as chiral modifiers in the Rh(I) catalyzed [4+2] cycloisomerization reaction results in moderate to goo
Related Papers (5)
Rhodium catalyzed intramolecular [4+2] cycloisomerization reactions
On the asymmetric rh(I) catalyzed [4+2] cycloisomerization reaction. Electronic and torsional ligand control of absolute stereoselection.
Lydia McKinstry,Tom Livinghouse +1 more
Nickel-catalyzed intramolecular [4+2] dienyne cycloadditions: an efficient new method for the synthesis of polycycles containing cyclohexa-1,4-dienes
Paul A. Wender,Thomas E. Jenkins +1 more