Journal ArticleDOI
Rhodium-catalyzed oxidative olefination of C-H bonds in acetophenones and benzamides.
Reads0
Chats0
About:
This article is published in Angewandte Chemie.The article was published on 2011-02-01. It has received 402 citations till now. The article focuses on the topics: Heck reaction & Amination.read more
Citations
More filters
Journal ArticleDOI
Catalytic dehydrogenative cross-coupling: forming carbon-carbon bonds by oxidizing two carbon-hydrogen bonds
Charles S. Yeung,Vy M. Dong +1 more
Journal ArticleDOI
Towards mild metal-catalyzed C–H bond activation
TL;DR: This critical review summarizes and discusses endeavours towards the development of mild C-H activation methods and wishes to trigger more research towards this goal.
Journal ArticleDOI
C–C, C–O and C–N bond formation via rhodium(III)-catalyzed oxidative C–H activation
Guoyong Song,Fen Wang,Xingwei Li +2 more
TL;DR: The facile construction of C-E (E = C, N, S, or O) bonds makes Rh(III) catalysis an attractive step-economic approach to value-added molecules from readily available starting materials.
Journal ArticleDOI
Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups
TL;DR: In this article, a review of the development of utilizing functionalities as directing groups for the construction of C-C and C-hetero bonds via C-H activation using various transition metal catalysts is presented.
Journal ArticleDOI
Rhodium catalyzed chelation-assisted C-H bond functionalization reactions
TL;DR: In several cases the methods that the group has developed for chelation-controlled C-H bond functionalization have been applied to the total synthesis of complex molecules such as natural products, highlighting the utility of these methods in organic synthesis.
References
More filters
Journal ArticleDOI
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
TL;DR: This is the first comprehensive review encompassing the large body of work in this field over the past 5 years, and will focus specifically on ligand-directed C–H functionalization reactions catalyzed by palladium.
Journal ArticleDOI
Catalytic functionalization of arenes and alkanes via C-H bond activation.
TL;DR: Several novel synthetic reactions of arenes and alkanes discovered and investigated in the laboratory are summarized here.
Journal ArticleDOI
Efficient catalytic addition of aromatic carbon-hydrogen bonds to olefins
Shinji Murai,Fumitoshi Kakiuchi,S. Sekine,Yasuo Tanaka,Asayuki Kamatani,Motohiro Sonoda,Naoto Chatani +6 more
TL;DR: The selective cleavage of carbon-hydrogen bonds in organic compounds is a critical step in many organic syntheses, and is particularly important in the conversion of hydrocarbons to useful organic compounds.
Journal ArticleDOI
A Meta-Selective Copper-Catalyzed C–H Bond Arylation
TL;DR: A copper-catalyzed arylation reaction is developed that selectively substitutes phenyl electrophiles at the aromatic carbon–hydrogen sites meta to an amido substituent and is applicable to a broad range of aromatic compounds.
Journal ArticleDOI
Efficient Activation of Aromatic C-H Bonds for Addition to C-C Multiple Bonds
TL;DR: Efficient electrophilic metalation of aromatic C-H bonds leading to new C-C bond formation through regio- and stereoselective addition to alkynes and alkenes has been realized by a catalytic amount of palladium( II) or platinum(II) compounds in a mixed solvent containing trifluoroacetic acid at room temperature.
Related Papers (5)
Rhodium-Catalyzed C-C Bond Formation via Heteroatom-Directed C-H Bond Activation
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis
Tetsuya Satoh,Masahiro Miura +1 more