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Sequential extraction of copper from soils and relationships with copper in maize

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TLDR
In this paper, the copper concentration of maize at maturity stage reached values from 36.3 to 65.9 µg kg−1 compared to copper levels usually found in non-contaminated crops.
Abstract
We studied copper uptake by maize grown on soils that have been contaminated with CuSO4. In soil the total copper level ranged from 24 to 135 mg kg−1. The copper distribution in soil fractions was assessed by sequential extraction, showing that anthropogenic copper is mainly concentrated in oxides fractions. The copper concentration of maize at the maturity stage reached values from 36.3 to 65.9 mg kg−1 compared to copper levels usually found in non-contaminated crops (5–30 mg kg−1). Here we demonstrate that copper can be accumulated by maize and that copper concentration in maize can be predicted by equations including copper concentration of soil fractions.

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Citations
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Copper contamination of vineyard soils from small wine producers: A case study from the Czech Republic

TL;DR: In this article, the authors focused on evaluating metal contamination of vineyard soils from small wine producers from the Czech Republic using chemical fractionation analyses and found that the highest Cu concentrations were found in the soil from the non-active vineyard, suggesting that contamination of soils from abandoned vineyards should be investigated before changing their use in agriculture.
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Bioaccumulation and biosorption efficacy of Trichoderma isolate SP2F1 in removing copper (Cu(II)) from aqueous solutions

TL;DR: Results here showed that Trichoderma spp isolate SP2F1 has good potential for application in Cu(II) removal, can be used to treat sewage waste by applying either in viable or non-viable cell forms.
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Spatial distribution and chemical partitioning of potentially toxic elements in soils around Khatoon-Abad Cu Smelter, SE Iran

TL;DR: In this article, the environmental impacts of Khatoon Abad Cu smelter, SE Iran, on soil contamination and to investigate the chemical partitioning of potentially toxic elements (As, Cd, Cu, Mo, Pb and Zn) in the soils.
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Free Cu2+ Ions, Cu Fractionation and Microbial Parameters in Soils from Apple Orchards Following Long-Term Application of Copper Fungicides

TL;DR: In this paper, the free Cu 2+ ion activity in soil solution and the soil Cu fractionation in the solid phase following long-term application of copper fungicide, Bordeaux mixture, in apple orchards was investigated.
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Potential for phytoextraction of copper by Sinapis alba and Festuca rubra cv. Merlin grown hydroponically and in vineyard soils

TL;DR: The capacity of Festuca rubra cv Merlin and Sinapis alba to tolerate and accumulate copper (Cu) was first investigated in a hydroponic system without the interference of soil chemical–physical properties to reduce excess Cu in vineyard soils.
References
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Journal ArticleDOI

Fractionation method for soil microelements

L.M. Shuman
- 01 Jul 1985 - 
TL;DR: In this paper, a sequential extraction procedure to separate chemical forms of soil microelements was used to separate sand, silt, and clay sizes, and each was dissolved and analyzed for the above elements.
Journal ArticleDOI

Biochemical, physiological, and structural effects of excess copper in plants

TL;DR: Copper effects on plant physiology are wide ranging, including interference with fatty acid and protein metabolism and inhibition of respiration and nitrogen fixation processes, and at the whole plant level Cu is an effective inhibitor of vegetative growth and induces general symptoms of senescence.
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Evaluation of heavy metal availability in polluted soils by two sequential extraction procedures using factor analysis.

TL;DR: Cd, Cu and Zn labile levels were related to total metal grass contents indicating its suitability for the availability studies in polluted soil-plant system, as well as between the levels of the different sequential fractions and the total content in grass.
Journal ArticleDOI

Trace metal speciation and bioavailability in urban soils.

TL;DR: P pH and total metals in soil were significantly correlated with the activities of free metal ions, except for Cd(2+), which only had a weak correlation with soil pH.
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Here we demonstrate that copper can be accumulated by maize and that copper concentration in maize can be predicted by equations including copper concentration of soil fractions.