Journal ArticleDOI
Solute‐Solute Interactions in Aqueous Solutions
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In this article, the authors interpreted solvent-solute interactions in aqueous solutions of nonelectrolytes using both lattice and distribution function theories of the dissolved state.Abstract:
Solute‐solute interactions in aqueous solutions of nonelectrolytes are interpreted using both lattice and distribution function theories of the dissolved state. Experimental activity data of high precision can be obtained from the literature for aqueous solutions of many nonelectrolytes. If the logarithm of the solvent activity coefficient (γ1) is expressed as a power series in the mole fraction of the solute (x2), lnγ1 = Bx22 + Cx23 + ···, then the coefficients B and C can be determined analytically from the experimental measurements. Values of B were obtained for 52 aqueous mixtures; values of C were obtained for 39 of these mixtures. The solutes considered include aliphatic alcohols, amines, amides, ketones, fatty acids, amino acids, and sugars. In some cases, experimental data were available from which the temperature dependence of the quantities B and C could also be determined. The effect of solute size on the coefficients B and C was investigated using the lattice theories of Flory, Huggins, and Gu...read more
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Solute–solute interactions in water. II. An analysis through the Kirkwood–Buff integrals for 14 organic solutes
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References
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Journal ArticleDOI
Application of the Methods of Molecular Distribution to Solutions of Large Molecules
TL;DR: In this article, the thermodynamic potentials of the solvent in solutions of ordinary organic molecules are extended to solutions of large molecules by methods using continuous molecular distribution functions, and a general expression is developed for A2 for flexible chain molecules in terms of the interactions of the segments of the chains.
Journal ArticleDOI
Measurements of heat capacity and heat of vaporization of water in the range 0 degrees to 100 degrees C
Journal ArticleDOI
Activity coefficients in aqueous solutions of sucrose, mannitol and their mixtures at 25°
R. A. Robinson,R. H. Stokes +1 more
Journal ArticleDOI
Activity, Density, and Relative Viscosity Data for Several Amino Acids, Lactamide, and Raffinose in Aqueous Solution at 25°
Journal ArticleDOI
The Structure of the Carboxyl Group: I. The Investigation of Formic Acid by the Diffraction of Electrons.
Linus Pauling,L. O. Brockway +1 more
TL;DR: The investigation reported in this paper has verified the resonating structure by the determination of interatomic distances in formic acid, and shown that in the dimer of formic Acid the molecules are joined together by hydrogen bonds between the oxygen atoms of the carboxyl groups.
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