Journal ArticleDOI
Some organic reactions promoted by samarium diiodide
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TLDR
In this article, the reaction between aldehydes and allylic or benzylic halides in the presence of samarium diiodide was studied and the reactivities of various nitrogen functional groups (imine, oxime, nitro, azo, cyano) towards SmI2 were also examined.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1983-07-05. It has received 142 citations till now. The article focuses on the topics: Organic reaction & Imine.read more
Citations
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Coupling of Organic Halides with Carbonyl Compounds Promoted by SmI2, the Kagan Reagent
Alain Krief,A.‐M. Laval +1 more
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Twenty-five years of organic chemistry with diiodosamarium: an overview
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Samarium Diiodide Mediated Reactions in Total Synthesis
TL;DR: This Review highlights selected applications of SmI(2) in total synthesis, with special emphasis on novel transformations and mechanistic considerations.
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Oxime and oximate metal complexes: unconventional synthesis and reactivity
TL;DR: The metal-mediated reactions of oxime/oximato metal compounds have been investigated actively since the beginning of 20th century and aspects such as traditional synthetic routes leading to oxime and oximato complexes, structural and solution chemistry and analytical applications have been reviewed extensively.
References
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Journal ArticleDOI
Divalent lanthanide derivatives in organic synthesis. 1. Mild preparation of samarium iodide and ytterbium iodide and their use as reducing or coupling agents
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New reagents for the intermolecular and intramolecular pinacolic coupling of ketones and aldehydes
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Highly Selective Carbon-Carbon Bond Forming Reactions Mediated by Chromium(II) Reagents
TL;DR: A low valent chromium reagent is generated from chromium(III) chloride and a half mol of lithium aluminum hydride in tetrahydrofuran as mentioned in this paper, which behaves similarly to anhydrous chromium (II) chloride, which is commercially available, and reduces allylic halides to produce unisolable allylchromium species which add efficiently to aldehydes or ketones with high degree of stereo and chemoselectivity.