Journal ArticleDOI
Some Typical Advances in the Synthetic Applications of Allenes
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This article is published in Chemical Reviews.The article was published on 2005-06-09. It has received 1085 citations till now.read more
Citations
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Journal ArticleDOI
Catalytic Functionalization of Indoles in a New Dimension
Marco Bandini,Astrid Eichholzer +1 more
TL;DR: This Review emphasizes the achievements in the selective catalytic functionalization of indoles (C-C bond-forming processes) over the last four years.
Journal ArticleDOI
Coinage Metal-Assisted Synthesis of Heterocycles
TL;DR: The chiral stationary phase for Heterocycloaddition showed good chiral recognition ability towards various racemates, including N/O-Vinylation/Arylation and Radical Cyclization of Haloalkenes and Haloalkynes.
Journal ArticleDOI
Gold-catalyzed nucleophilic cyclization of functionalized allenes: a powerful access to carbo- and heterocycles.
Norbert Krause,Christian Winter +1 more
TL;DR: This account comprises gold-catalyzed cyclization reactions of allenes by attack of carbon or heteroatom nucleophiles, which are particularly well suited for the selective activation of allene in the presence of other reactive functionalities.
Journal ArticleDOI
Transition Metal-Mediated Synthesis of Monocyclic Aromatic Heterocycles
TL;DR: The present review is a transition metal-catalyzed synthesis of aromatic monocyclic heterocycles, aiming at achieving greater levels of molecular complexity and better functional group compatibilities in a convergent and atom economical fashions from readily accessible starting materials and under mild reaction conditions.
Journal ArticleDOI
Transition-Metal-Catalyzed Cross-Couplings through Carbene Migratory Insertion
Ying Xia,Di Qiu,Jianbo Wang +2 more
TL;DR: This review will summarize the achievements made in cross-coupling area since 2001 and identify the new organometallic species generated from migratory insertion that may undergo various transformations.
References
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BookDOI
Handbook of organopalladium chemistry for organic synthesis
TL;DR: Palladium-CATALYZED Reactions Involving Nucleophilic Attack on -Ligands of Palladium-Alkene, PalladiumAlkyne, and Related Derivatives as mentioned in this paper.
Journal ArticleDOI
Palladium-catalyzed reactions of allenes.
Journal ArticleDOI
Non-Metathesis Ruthenium-Catalyzed C−C Bond Formation
Journal ArticleDOI
Synthesis and Properties of Allenic Natural Products and Pharmaceuticals
TL;DR: Inspired by the intriguing biological activities of many allenic natural products, allene moieties are now systematically introduced in pharmacologically active classes of compounds (steroids, prostaglandins, amino acids, nucleosides) and often exhibit impressive activities as mechanism-based enzyme inhibitors, cytotoxic, or antiviral agents.
Journal ArticleDOI
An Expedient Phosphine-Catalyzed [4 + 2] Annulation: Synthesis of Highly Functionalized Tetrahydropyridines
Xue-Feng Zhu,Jie Lan,Ohyun Kwon +2 more
TL;DR: Mechanistic reasoning for this new annulation has led to an expansion of the reaction scope by employing ethyl 2-(substituted-methyl)-2,3-butadienoates to give Ethyl 2,6-cis-disubst ituted-1-(4-tosyl)-1,2,5, 6-tetrahydro-pyridine-3-carboxylates with high diastereoselectivities.
Related Papers (5)
Transition Metal-Catalyzed/Mediated Reaction of Allenes with a Nucleophilic Functionality Connected to the α-Carbon Atom
Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses
Shichao Yu,Shengming Ma +1 more