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Stability, infrared spectrum and magnetic properties of FeBO3

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TLDR
In this article, the stability of the compound FeBO3 with the calcite structure and Fe3BO6 with norbergite structure has been determined using magnetic measurements on polycrystalline FBO3 revealed the compound to be a weak ferromagnet with a high anisotropic field below 115°C.
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This article is published in Materials Research Bulletin.The article was published on 1968-08-01. It has received 65 citations till now. The article focuses on the topics: Norbergite & Infrared spectroscopy.

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Room‐Temperature Ferromagnetic Materials Transparent in the Visible

TL;DR: The only known crystals which have spontaneous ferromagnetic moment at room temperature and are transparent well into the visible spectrum are ferric borate, FeBO3, and ferric fluoride, FeF3 as mentioned in this paper.
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MAGNETO‐OPTICAL PROPERTIES OF A GREEN ROOM‐TEMPERATURE FERROMAGNET: FeBO3

TL;DR: Ferric fluoride (FeF3) is a transparent green uniaxial weak ferromagnet with a Curie temperature of 365 °K as mentioned in this paper, which is the only known material which has spontaneous magnetic moment at room temperature.
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Determination of coordinations and coordination-specific site occupancies by electron energy-loss spectroscopy: An investigation of boron—oxygen compounds

TL;DR: In this paper, a quantitative method to derive the coordination-specific boron site occupancies from B1s spectra taken from complex borates containing both coordinations is presented.
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Critical‐Point Behavior of FeBO3 Single Crystals by Mössbauer Effect

TL;DR: Mossbauer effect (ME) measurements of the hyperfine (hf) interaction in single crystals of FeBO3, have been used to study the behavior of the sublattice magnetization near the Neel temperature.
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Structure magnetique du metaborate de fer FeBO3

TL;DR: In this article, the borate de fer FeBO 3 a structure calcite s'ordonne antiferromagnetiquement avec a temperature of Neel de 348°K.
References
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Journal ArticleDOI

Infrared Spectra of the Crystalline Inorganic Borates.

TL;DR: From correlations between spectra and structure it appears that boron in 3-fold or in 4-fold coordination can be identified with reasonable assurance on the basis of the infrared spectrum alone.
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Metamagnetism of Siderite (FeCO3)

TL;DR: In this paper, it was shown that a uniaxial antiferromagnet with high anisotropy should show a sharp transition to a ferromagnetic configuration in fields sufficient to overcome the antiferromeagnetic exchange.