Journal ArticleDOI
Stereoselective synthesis of 1-substituted organometallic derivatives of 3,3-dimethylbutane-1,2-d2
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This article is published in Journal of the American Chemical Society.The article was published on 1974-05-01. It has received 46 citations till now.read more
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Journal ArticleDOI
Single-molecule spectroscopy of interfacial electron transfer.
TL;DR: This report shows how SMS can be used to measure photoinduced interfacial electron transfer (IET) and back electron transfer rates in a prototypical chromophore-bridge-electrode nonadiabatic electron transfer system and results have implications for molecular electronics.
Book ChapterDOI
Chiral Metal Atoms in Optically Active Organo-Transition-Metal Compounds
TL;DR: In this article, an important approach to stereochemical problems is to make use of the concept of chirality, which is the chiral center most frequently encountered is the asymmetric carbon atom, a tetrahedral C atom.
Book ChapterDOI
B12 and Related Organocobalt Chemistry: Formation and Cleavage of Cobalt Carbon Bonds
P. J. Toscano,Luigi G. Marzilli +1 more
Journal ArticleDOI
Organocobaloximes: cobalt-carbon bond stability and synthesis
B. D. Gupta,Sujit Roy +1 more
TL;DR: A complete analysis of the synthetic aspects of organocobalt compounds and organocobaloximes, in particular, is undertaken in this paper, where the stability of the Co-Sigma bond, general methods of synthesis and experimental procedures are discussed.
Journal ArticleDOI
Porphines de cobalt a liaison cobalt—carbone: synthese, reaction avec l'oxygene moleculaire et etude electrochimique
TL;DR: In this paper, a photolysis of these compounds in the presence of molecular oxygen yield new complexes for which structure ROOCoTPP (II) is assumed, and Electrochemical studies of complexes I and II are reported.