scispace - formally typeset
Journal ArticleDOI

Structural and chemical characterization of a phosphine bound M-H-M bridged carbonylate: Et4N+(.mu.-H)[Mo2(CO)9PPh3]-

Marcetta Y. Darensbourg, +4 more
- 01 May 1979 - 
- Vol. 101, Iss: 10, pp 2631-2637
About: 
This article is published in Journal of the American Chemical Society.The article was published on 1979-05-01. It has received 9 citations till now. The article focuses on the topics: Phosphine.

read more

Citations
More filters
Book ChapterDOI

Crystallographic studies of transition metal hydride complexes

Raymond G. Teller, +1 more
Book ChapterDOI

Anionic Transition Metal Hydrides

Marcetta Y. Darensbourg, +1 more
- 01 Jan 1987 - 
TL;DR: A review of the anionic transition-metal hydrides can be found in this paper, where the X-ray diffraction study revealed a distorted octahedral disposition of ligands about Ru.
Journal ArticleDOI

X-ray diffraction studies of the influence of lattice effects on the metal carbonyl framework of the [Mo2(CO)10(μ-H)]− monoanion

Jeffrey L. Petersen, +2 more
- 17 Mar 1981 - 
TL;DR: In this article, the influence of lattice effects upon the anion's solid-state geometry was examined and it was shown that the [Mo 2 (CO) 10 (μ-H)] − anion can adopt either a linear, eclipsed ([Et 4 N] + salt) or an appreciably bent, staggered configuration with the degree of bending dictated by the choice of the cation.
Journal ArticleDOI

Dinuclear molybdenum carbonyls bridged by hydride ligands

Jiann T. Lin, +4 more
- 08 Feb 1994 - 
Journal ArticleDOI

A dinuclear Mo2H8 complex supported by bulky C5H2tBu3 ligands.

Yasuhiro Ohki, +5 more
- 21 Jul 2020 - 
TL;DR: A dinuclear Mo2H8 complex supported by bulky C5H2tBu3 ligands is synthesized from the reaction of Cp‡MoCl4 with KC8 under H2 and the hydrides of complex 1 can be replaced with benzene at 60 °C to afford a μ-benzene complex C p‡2Mo2H2(μ-C6H6) (2).
Related Papers (5)

Transition-metal derivatives of the functionalized cyclopentadienyl ligand. XVI. Synthesis of the bridged complexes [(µ-η5-C5H4PPh2)M(CO)2]2 (M=Cr, Mo, W). X-Ray crystal structure of the dihydride derivative [(µ-η5-C5H4PPh2)W(CO)2H]2

Brigitte Brumas-Soula, +2 more
- 01 Jan 1998 - 

Coordinated tautomers of a bis-(phosphoryl)-phosphine: assemblage of group VIB metal complexes containing diphosphoxane (POP) linkages

Edward H. Wong, +2 more
- 15 Mar 1983 - 

Reactivity of the ansa-Bridged Metallocene Dichlorides [X(η5-C5H4)2]MCl2 (X = SiMe2, CMe2; M = Mo, W) toward Metallophosphide Anions [PPh2M‘(CO)x]- (M‘ = Cr, Mo, W, x = 5; M‘ = Fe, x = 4). Formation of Heterobimetallic Complexes by Nucleophilic Substitution on a Cyclopentadienyl Ligand or on the Metal M

Virginie Comte, +3 more
- 23 Dec 1997 - 

Molybdenum carbonyl complexes of diphenylphosphinous acid and diphenylphosphinous acid derivatives. Crystal and molecular structures of [Et4N][Mo(CO)4(PPh2O)2H]·0.37 CH2Cl2, Mo(CO)4(PPh2OH)(PPh2OCH2CH2NMe2)·H2O and Mo(CO)4(PPh2SPPh2)

F. Albert Cotton, +4 more
- 15 Feb 1984 - 

47-Electron Organometallic Clusters. Synthesis, Characterization, and Reactivity toward Electrophiles/Oxidants of H2Ru3(RC2R')(CO)6(PPh3)3 and Crystal Structures of (.mu.-H)2Ru3(.mu.3-.eta.2-EtCCEt)(CO)7(PPh3)2 and (.mu.-H)2Ru3(.mu.3-.eta.2-EtCCEt)(CO)6(PPh3)3.cntdot.3CH2Cl2

Witold Paw, +3 more
- 01 Aug 1995 -