Journal ArticleDOI
Studies of the deposition of cadmium on foreign substrates
TLDR
In this paper, the potential sweep diagrams were characterized by a loop exhibiting an inductive nature and two maxima on the anodic branch of the voltammogram could be attributed to the dissolution of non-epitaxial and epitaxial deposits.About:
This article is published in Electrochimica Acta.The article was published on 1977-05-01. It has received 11 citations till now. The article focuses on the topics: Cadmium Deposition & Underpotential deposition.read more
Citations
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Journal ArticleDOI
Observation of Uniaxial Structures of Underpotentially Deposited Cadmium on Au(111) with in Situ Scanning Tunneling Microscopy
TL;DR: In this paper, the atomic structures of several distinct adlayers of Cd underpotentially deposited onto a Au(111) surface in sulfuric acid electrolyte were revealed by in situ scanning tunneling microscopy (STM).
Journal ArticleDOI
Electrochemical nucleation: Part V. Electrodeposition of cadmium onto vitreous carbon and tin oxide electrodes
TL;DR: In this paper, the electrochemical nucleation of cadmium onto vitreous carbon and onto tin oxide electrodes was studied using potentiostatic methods and the influence of supporting electrolyte was investigated.
Journal ArticleDOI
The secondary lithium—aluminium electrode at room temperature. II. Kinetics of the electrochemical formation of the lithium—aluminium alloy
TL;DR: The kinetics of the electrochemical formation of lithium-aluminium alloy was studied by voltammetric, potentiostatic, and pulse galvanostatic techniques in 1M LiClO4-propylene carbonate solutions as mentioned in this paper.
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The secondary lithium—aluminium electrode at room temperature: I. Cycling in LiClO4—propylene carbonate solutions
TL;DR: In this article, the cyclability of Li-Al electrodes in 1M LiClO 4 -propylene electrolyte solutions has been studied at current densities up to 8 mA/cm 2, charge densities of up to 4 C/mm 2, and with up to 100 C/ cm 2 of initially deposited lithium.
Journal ArticleDOI
Signal enhancement of potentiometric stripping analysis using digital signal processing
TL;DR: In this article, four digital signal processing methods, moving average smoothing, polynomial smoothing and rectangular low pass filtering, have been compared in this study of potentiometric stripping analysis (PSA) data.
References
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Journal ArticleDOI
Underpotential deposition of metals and work function differences
TL;DR: In this article, the potential difference between monolayer and bulk deposition is closely related to the difference in the work functions of substrate and deposit, causing a partial charge of the adatoms.
Journal ArticleDOI
Experimental determination and interpretation of the electrosorption valency γ
J.W. Schultze,K.J. Vetter +1 more
TL;DR: In this article, a short review concerning the definition of the electrosorption valency γF = (∂μh/∂Δϑ)Г = −(∂qm/ ∂Г)Δπ is given.
Journal ArticleDOI
Optical and Electrochemical Studies of Underpotential Deposition of Lead on Gold Evaporated and Single‐Crystal Electrodes
TL;DR: In this article, linear sweep voltammetry and reflectance spectroscopy have been used to examine the underpotential deposition of lead on gold in Pb2+; containing solutions.
Journal ArticleDOI
The Formation of Monolayer Metal Films on Electrodes
TL;DR: In this article, the two-dimensional nucleation and the metal ion adsorption process are discussed as initial steps for electrocrystallization on the same or on a foreign substrate.
Journal ArticleDOI
Kinetics of the Deposition and Dissolution of Silver
A. R. Despic,J. O'm. Bockris +1 more
TL;DR: In this paper, a theoretical analysis of the steady state of surface diffusion control of the metal-ion exchange reaction shows that the current is distributed nonuniformly between growing sites, with constant potential over the electrode surface.
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Optical and electrochemical studies of the under-potential deposition of metals
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