Journal ArticleDOI
Studies on the polymerization of ethyl acrylate. III. Effect of temperature on the solvent‐transfer reaction
P. V. T. Raghuram,U. S. Nandi +1 more
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In this article, the effect of temperature on transfer constants for different solvents in the polymerization of ethyl acrylate was observed and activation energy differences (EtrS − Ep) and frequency factors were computed.Abstract:
The effect of temperature on transfer constants for different solvents in the polymerization of ethyl acrylate was observed. Activation energy differences (EtrS − Ep) and frequency factors were computed. It is observed that high frequency factors are associated with high activation energies. Values of EtrS were calculated by an approximate method and were compared with the available data on methyl methacrylate, isobutyl methacrylate, and styrene.read more
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A Comprehensive Simulator/Database Package for Reviewing Free-Radical Homopolymerizations
J. Gao,Alexander Penlidis +1 more
TL;DR: This work simulates free-radical homopolymerizations under restricted polymerization conditions with real-world examples of several different types of monomer systems.
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Thermisch initiierte Addition von Alkanen an Alkene, II. Addition von Cyclohexan an Acrylester in einer freien Radikalkettenreaktion
TL;DR: In this article, the addition of cyclohexane to phenyl acrylate showed that a free radical chain reaction is involved, which can only be satisfactorily explained in terms of a symproportionation of the alkane and the alkene to give two alkyl radicals.
Journal ArticleDOI
Impact of side reactions on molar mass distribution, unsaturation level and branching density in solution free radical polymerization of n-butyl acrylate under well-defined lab-scale reactor conditions
TL;DR: In this paper, a kinetic Monte Carlo modeling study is presented to enhance the understanding of solution free radical polymerization of n-butyl acrylate (nBuA) in the presence of β-scission.
Journal ArticleDOI
Jacket temperature regulation allowing well-defined non-adiabatic lab-scale solution free radical polymerization of acrylates
TL;DR: In this paper, a tree-based kinetic Monte Carlo (kMC) model for radical acrylate polymerization chemistry with an energy balance was proposed to predict non-isothermal conditions in the presence and absence of jacket temperature modifications.