Journal ArticleDOI
Superdrawn crystalline polymers: A new class of high‐strength fiber
Edward S. Clark,L. S. Scott +1 more
TLDR
A new kind of acetal fiber has been discovered which has a tensile strength of 1.7 GPa (250,000 psi) and an elastic modulus of 35 GPa(5 × 106 psi) as mentioned in this paper.Abstract:
A new kind of acetal fiber has been discovered which has a tensile strength of 1.7 GPa (250,000 psi) and an elastic modulus of 35 GPa (5 × 106 psi). This fiber is produced by a special two-stage drawing process in the solid state which requires careful control of deformation rate and temperature. Previously known drawn fibers are reported to consist of folded-chain blocks joined by a limited number of tie-molecules. It is hypothesized that the second stage of the novel drawing process eliminates the lamella (block) surfaces which act as strength-limiting stress concentrators. A new type of fiber is created in which any remaining chain-folds are distributed as defects in a continuous crystal matrix. It is the continuity of the crystal matrix which is believed responsible for the remarkable properties of the fiber.read more
Citations
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Journal ArticleDOI
Ultra-high-strength polyethylene filaments by solution spinning/drawing
Paul Smith,PJ Piet Lemstra +1 more
TL;DR: In this paper, the influence of the draw ratio on the mechanical and thermal properties of polyethylene fibres was investigated, and it was found that the tensile strength tended to approach an upper limit at high draw ratios.
Journal ArticleDOI
The structure of thermotropic copolyesters
Linda C. Sawyer,Michael Jaffe +1 more
TL;DR: In this article, a hierarchical structural model is proposed for a broad range of oriented fibres, extrudates and moulded articles. And the defect hierarchy is defined by the regular meander of the molecular chain and a localization of defects within a microfibril at about a 50 nm periodicity.
Journal ArticleDOI
Ultrahigh-strength polyethylene filaments by solution spinning and hot drawing
TL;DR: In this paper, the authors describe some preliminary results on alternative routes to produce high-strength and high-modulus polyethylene filaments with a uni-axial Young's modulus of 90 GPa and a tensile strength of 3 GPa.
Journal ArticleDOI
Maximum strength and drawing mechanism of hot drawn high molecular-weight polyethylene
B. Kalb,Albert J. Pennings +1 more
TL;DR: In this paper, an investigation of the hot drawing of high molecular weight polyethylene fibres containing a substantial amount of solvent, and of fibres with a porous structure that were dried after solution spinning, was conducted.
Book ChapterDOI
The preparation, structure and properties of ultra-high modulus flexible polymers
TL;DR: In this article, the preparation, structure and properties of ultra-high modulus polyolefins are discussed and detailed consideration is given to the preparation of ultra high modulus fibres by spinning from dilute solution and by gel-spinning and hot drawing.
References
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Journal ArticleDOI
Properties of Ultra-high Modulus Linear Polyethylenes
G. Capaccio,I. M. Ward +1 more
TL;DR: In this article, the effect of molecular weight and molecular weight distribution on the cold drawing behavior of linear polyethylene was studied and some of the results seem to be sufficiently unusual to warrant reporting at this stage.
Journal ArticleDOI
Nylon 6 fibers: Changes in structure between moderate and high draw ratios
TL;DR: In this article, the in-phase modulus and coefficient of diffusion of nylon 6 fibers were analyzed in terms of wide-and small-angle X-ray diffraction data in directions parallel and perpendicular to the fiber axis.
Journal ArticleDOI
The properties of polyethylene crystallized under the orientation and pressure effects of a pressure capillary viscometer
John H. Southern,Roger S. Porter +1 more
TL;DR: In this article, high-density commercial polyethylenes have been crystallized under the combined orientation and pressure effects available in the Instron capillary rheometer, and the samples so formed were found to have a high degree of crystal perfection and crystal orientation in combination with the unusual property of transmitting visible light.
Journal ArticleDOI
Relationship of structure and morphology to properties of “hard” elastic fibers and films
TL;DR: In this article, it was discovered that highly crystalline polymers such as polypropylene and polyoxymethylene could be extruded in such a manner a s to produce remarkably elastic fibers and films which appeared superficially to behave like rubber or Spandex-type elastomers.
Journal ArticleDOI
Polymer texture: The arrangement of crystallites
TL;DR: In this article, the structural arrangement of oriented crystalline polymers is studied based on the data from x-ray diagrams at small angles, combined with crystallite dimensions measured from wide-angle xray patterns, and the amount of close packing is variable; it is optimal after a relaxation treatment.
Related Papers (5)
Preparation of ultra-high modulus linear polyethylenes; effect of molecular weight and molecular weight distribution on drawing behaviour and mechanical properties
G. Capaccio,I. M. Ward +1 more