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Surface acidity of pyrophyllite and talc

D. Y. Wu, +3 more
- 01 Jan 1992 - 
- Vol. 8, Iss: 6, pp 367-379
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TLDR
For example, this article showed that water molecules previously adsorbed on the surface of pyrophyllite and talc decreased both the strength and amount of acid sites, although the degrees of the decrease were smaller.
Abstract
Pyrophyllite and talc were shown to have acid sites on their surface, and the strength and amount of the acidity were much higher for pyrophyllite than talc. The strength and amount of the acidity of both minerals were not affected by the exchangeable cation species. Water molecules previously adsorbed on the surface of the minerals lowered both the strength and amount of the acid sites, although the degrees of the decrease were smaller than the case of montmorillonite. When the water was introduced after the adsorption of indicators, the water molecules did not affect voth the strength the amount of the acidity

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Role of Magnesium Silicates in Wet-Kneaded Silica-Magnesia Catalysts for the Lebedev Ethanol-to-Butadiene Process

TL;DR: In this article, the influence of Mg precursor and MgO content on morphology, chemical structure (as determined by TEM, FT-IR, XRD and solid-state 1H-29Si cross-polarized MAS NMR), and on catalyst performance is demonstrated.
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Asian dust increases radiocesium retention ability of serpentine soils in Japan.

TL;DR: In this paper, a series of pretreatments were performed to remove organic matter and hot sodium citrate was used to remove hydroxy-Al polymers (Al(OH)x).
References
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Surface Acidity of Smectites in Relation to Hydration, Exchangeable Cation, and Structure*

TL;DR: The NH4+ formed by the protonation process in different environments in the bentonite and nontronite clays are believed to be due to charge site location and its effects on ion hydration as discussed by the authors.
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