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Journal ArticleDOI

Surface reactions of oxygen ions. I. Dehydrogenation of alkanes by oxygen(1-) ions on magnesium oxide

Ken-ichi Aika, +1 more
- 01 Jul 1977 - 
- Vol. 81, Iss: 14, pp 1393-1398
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This article is published in The Journal of Physical Chemistry.The article was published on 1977-07-01. It has received 167 citations till now. The article focuses on the topics: Magnesium & Dehydrogenation.

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Journal ArticleDOI

Direct Conversion of Methane to Value-Added Chemicals over Heterogeneous Catalysts: Challenges and Prospects

TL;DR: This work focuses mainly on the fundamentals of C-H activation and analyzes the reaction pathways toward selective routes of OCM, MDA, and MTOAH to provide some insights into their reaction mechanisms and implications for future development of highly selective catalysts for direct conversion of methane to high value-added chemicals.
Journal ArticleDOI

Synthesis of ethylene and ethane by partial oxidation of methane over lithium-doped magnesium oxide

TL;DR: In this paper, it was shown that lithium-doped magnesium oxide (Li/MgO) in the presence of O2 has high activity for abstracting H from CH4 to form ·CH3 radicals.
Journal ArticleDOI

Generation of active oxygen species on solid surfaces. Opportunity for novel oxidation technologies over zeolites

TL;DR: In this article, a new concept related to a recent discovery of remarkable ability of Fe complexes stabilized in a ZSM-5 matrix to generate a new form of surface oxygen (α-oxygen) from N2O is discussed.
Book ChapterDOI

Characterization and Reactivity of Molecular Oxygen Species on Oxide Surfaces

TL;DR: This chapter discusses the characterization and reactivity of mononuclear oxygen species on oxide surfaces and there is evidence from the examples for some of the species that are stable at much higher temperatures and may play an important role in catalytic reactions.
Journal ArticleDOI

Conversion of Methane by Oxidative Coupling

TL;DR: In this article, the conversion of Methane by Oxidative Coupling is discussed. But it is not discussed in detail in this paper, nor is it discussed in this article.
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