Syntheses, structure and intercalation properties of low-dimensional phenylarsonates, A(HO3AsC6H5)(H2O3AsC6H5) (A = Tl, Na, K and Rb)
TLDR
In this paper, four low-dimensional phenylarsonates, A(HO3AsC6H5), H2O3A6H 5, Rb(4), K(3) and N(2) have been synthesized and characterized by X-ray diffraction, spectroscopic and thermal studies.Abstract:
Four new low-dimensional phenylarsonates, A(HO3AsC6H5)(H2O3AsC6H5) (A = Tl(1), Na(2), K(3) and Rb(4)), have been synthesized and characterized by X-ray diffraction, spectroscopic and thermal studies. They crystallize in triclinic unit cells and have approximately planar arrangement of A+ ions, coordinated to oxygen atoms of phenylarsonates, on both sides. Structure of thallium phenylarsonate as determined by single crystal X-ray diffraction, is one-dimensional, whereas those of alkalimetal analogues are two-dimensional. Successful intercalation reactions of compounds1 and2 with primaryn-alkyl amines have been demonstrated.read more
Citations
More filters
Journal ArticleDOI
Preparation, characterization and luminescent properties of europium oxide doped nano LaMn0⋅9Zn0⋅1O3+d by sol-gel processing
TL;DR: In this paper, X-ray powder diffraction (XRD), fourier transform infrared spectroscopy (FT-IR) and photoluminescence spectra (PL) were used to characterize the resulting nanoparticles.
Journal ArticleDOI
Syntheses and Characterization of Silver Phenylphosphonates and Phenylarsonates, AgxH4–x(O3PPh)2 (x = 1–4) and AgxH4–x(O3AsPh)2 (x = 2, 4)
TL;DR: In this paper, a ladder-type structural framework of known isostructural ammonium phenylphosphonate compounds has been constructed for the first time using powder XRD, thermogravimetric and spectroscopic techniques.
Journal ArticleDOI
Monovalent metal phenylphosphonates and phenylarsonates: Single crystal X-ray structures of A(HO3PPh)(H2O3PPh) (A = K, Rb, Cs, Tl) and Na(HO3AsPh)(H2O3AsPh) and methylamine intercalation of A(HO3PPh)(H2O3PPh) (A = Li, Na, K, Tl)
TL;DR: In this paper, single crystal X-ray structures of known A (HO 3 PPh)(H 2 O 3PPh) (A = K, Rb, Cs, Tl, NH 4 ) compounds have been determined.
Journal ArticleDOI
A two‐dimensional silver(I) coordination polymer constructed from 4‐aminophenylarsonate and triphenylphosphane: poly[[(μ3‐4‐aminophenylarsonato‐κ3N:O:O)(triphenylphosphane‐κP)silver(I)] monohydrate]
TL;DR: The title compound, {[Ag(C6H7AsNO3)(C18H15P)]·H2O}n, has been synthesized from the reaction of 4-aminophenylarsonic acid with silver nitrate, in aqueous ammonia, with the addition of triphenylphosphane (PPh3).
Journal ArticleDOI
Non-molecular monovalent metal organophosphonates and diphosphonates
TL;DR: The solid state chemistry of non-molecular monovalent metal organophosphonate and diphosphonates is relatively new and evolving research arena as mentioned in this paper, and the syntheses and structural characterization of about fifty such compounds are reported in the literature.
References
More filters
Book
Spectrometric identification of organic compounds
TL;DR: In this paper, a sequence of procedures for identifying an unknown organic liquid using mass, NMR, IR, and UV spectroscopy is presented, along with specific examples of unknowns and their spectra.
Journal ArticleDOI
LAZY PULVERIX, a computer program, for calculating X‐ray and neutron diffraction powder patterns
K. Yvon,W. Jeitschko,E. Parthé +2 more
TL;DR: In this paper, a computer program has been written with the aim of calculating powder patterns without the use of crystallographic tables by deriving all symmetry information such as general equivalent positions from the Hermann-Mauguin space-group symbols.
Journal ArticleDOI
DIAMOND– Visual Crystal Structure Information System
Journal ArticleDOI
Crystalline Zr(R-PO3)2 and Zr(R-OPO3)2 compounds (R = organic radical)
TL;DR: By slowly decomposing zirconium fluoro-complexes in the presence of hydroxymethane phosphonic acid or triethylphosphate, micro-crystalline compounds with formulae Zr(HOCH 2 PO 3 ) 2 ·H 2 O, Zr 6 H 5 PO 3 ] 2 and Zr (C 2 H 5 OPO 3 )) 2 respectively are formed as mentioned in this paper.