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Synthesis of Unsaturated Organosilicon Compounds Via Alkene Metathesis and Metathesis Polymerization

Bogdan Marciniec and Cezary Pietraszuk
- 01 May 2003 - 
- Vol. 7, Iss: 8, pp 691-735
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This article is published in Current Organic Chemistry.The article was published on 2003-05-01. It has received 76 citations till now. The article focuses on the topics: Metathesis & Organosilicon.

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Catalysis by transition metal complexes of alkene silylation – recent progress and mechanistic implications

TL;DR: In this article, the mechanism of homogeneous catalysis for silylation of alkenes and silylalkynes with late transition metal complexes is discussed. But the authors focus on the synthesis of substituted vinyl-silicon functionalities.
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para-Octaiodophenylsilsesquioxane, [p-IC6H4SiO(1.5)]8, a nearly perfect nano-building block.

TL;DR: It is reported here that OPS reacts with ICl at sub-ambient temperatures to provide I8OPS in good yields and with excellent selectivity: >99% mono-iodo substitution with >93% para substitution as determined by H2O2/F- cleavage of the Si-C bonds to produce iodophenols.
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