Journal ArticleDOI
Temperature dependence of the rate constants for the addition of hydroxyl to benzene and to some monosubstituted aromatics (aniline, bromobenzene, and nitrobenzene) and the unimolecular decay of the adducts. Part 2. Kinetics into a quasi-equilibrium
F. Witte,E. Urbanik,Zetzsch. C. +2 more
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This article is published in The Journal of Physical Chemistry.The article was published on 1986-07-01. It has received 70 citations till now. The article focuses on the topics: Nitrobenzene & Aniline.read more
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A detailed mechanism for the gas-phase atmospheric reactions of organic compounds
TL;DR: In this paper, a gas-phase reaction mechanism for the atmospheric photooxidations of over 100 alkanes, alkenes, aromatic hydrocarbons, alcohols, ethers and other compounds representative of the range of reactive organics emitted into polluted atmospheres is described.
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A structure-activity relationship for the estimation of rate constants for the gas-phase reactions of OH radicals with organic compounds
TL;DR: In this paper, a technique for the calculation of rate constants for the gas-phase reactions of the OH radical with organic compounds has been updated and extended to include sulfur-and nitrogen-containing compounds.
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Adduct Formation of OH Radicals with Benzene, Toluene, and Phenol and Consecutive Reactions of the Adducts with NOx and O2
TL;DR: In this paper, the formation of the adducts of OH with benzene, toluene and phenol and consecutive reactions of the adsducts with NO, NO2 and O2 were investigated in the temperature range from ∼298-374 K employing the flash photolysis/resonance fluorescence technique in Ar at 133 mbar.
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The gas phase reactions of hydroxyl radicals with a series of aliphatic ethers over the temperature range 240–440 K
TL;DR: In this paper, the exact rate constants for the gas phase reactions of OH radicals with a series of linear aliphatic ethers using the flash photolysis resonance fluorescence technique were determined over the temperature range 240-440 K at total pressures between 25-50 Torr.
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The gas phase reactions of hydroxyl radicals with a series of esters over the temperature range 240–440 K
TL;DR: In this paper, the absolute rate constants for gas phase reactions of OH radicals with a series of esters using the flash photolysis resonance fluorescence technique were determined for the reaction mechanism.