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Journal ArticleDOI

The 2B1 ← 2A1 system of nitrogen dioxide☆

J.L. Hardwick, +1 more
- 01 Sep 1973 - 
- Vol. 21, Iss: 3, pp 458-461
TLDR
The vibrational structure of the 2B1 ← 2A1 system of NO2 has been assigned to a progression in ν′2. as mentioned in this paper showed that the bending potential function is expressed as a rapidly converging Taylor series expansion about the linear configuration.
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This article is published in Chemical Physics Letters.The article was published on 1973-09-01. It has received 100 citations till now.

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Citations
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Journal ArticleDOI

Hyperfine-resolved high-resolution laser spectroscopy of 14NO2 radical in the 15885 cm−1 energy region

TL;DR: In this paper, the rotational assignments of the A 2B2 ← X 2A1 transition of 14NO2 radical in the 15870-15900 cm−1 energy region were obtained by crossing a jet-cooled molecular beam and an output of a single-mode dye laser at the right angles.
Journal ArticleDOI

Normal Waves in a Metachiral Post Medium

TL;DR: In this paper, normal electromagnetic waves (Beltrami wave fields) in a metachiral medium with constitutive equations in the Post form are investigated, and expressions for wave numbers and wave impedance of propagating, and also evanescent, plane waves are derived.
Journal ArticleDOI

Potential Energy Surfaces of Nitrogen Dioxide for the Ground State

TL;DR: In this paper, the potential energy function of nitrogen dioxide with the C2v symmetry in the ground state is represented using the simplified Sorbie-Murrell many-body expansion function in terms of the symmetry of NO2.
Journal ArticleDOI

Surface Waves on an Impedance Plane in a Non-reciprocal Bi-isotropic Tellegen Medium

TL;DR: Propagation and attenuation constants of a plane monochromatic electromagnetic surface wave have been determined for propagation along a planar impedance surface bounding a half-space of a bi-isotropic Tellegen medium as discussed by the authors.
Journal ArticleDOI

Normal Waves in an Electromagnetic Metachiral Isotropic Medium with Losses

TL;DR: In this article, the difference between forward and backward normal waves is delineated by the introduction of a special parameter, the wave type identifier, and analytical expressions for the real and imaginary parts of the wave numbers of homogeneous normal waves are presented.
References
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Journal ArticleDOI

Determination of Molecular Structure from Microwave Spectroscopic Data

TL;DR: In this article, a method for determining the position of an atom in a molecule from spectroscopic measurements on two isotopic species of the molecule is described, and explicit expressions are derived for linear, symmetric top, planar, and nonplanar asymmetric top molecules.
Journal ArticleDOI

Microwave Spectrum of NO2: Fine Structure and Magnetic Coupling

TL;DR: The results obtained for 14N16O2 are: Rotational constantsA=239 868.7±11 Mc/secB= 13 000.12±0.6 Mc/ secC= 12 303.45±0 6.6Mc/secOdd electron expectation values with respect to (3ra2−1)/2r3〉=−1.73×1024cm−3N−nucleus〈(rb−irc)2/r3
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The absorption spectrum of no2 in the 3 700-4 600 a region,

TL;DR: In this article, an investigation of the absorption spectra of both 14NO2 and 15NO2 has revealed a long progression of red-degraded bands in the region 3 700 −4 600 A.
Journal ArticleDOI

Electronic Structure and Electronic Spectrum of Nitrogen Dioxide. III Spectral Interpretation

TL;DR: In this article, the excitation energies, potential energy surfaces, and oscillator strengths computed in the previous paper are discussed in light of experimentally reported spectroscopic data, namely absorption, fluorescence, chemiluminescence, predissociation, photolysis, and the absence of phosphorescence.
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