Journal ArticleDOI
The 2B1 ← 2A1 system of nitrogen dioxide☆
J.L. Hardwick,J.C.D. Brand +1 more
TLDR
The vibrational structure of the 2B1 ← 2A1 system of NO2 has been assigned to a progression in ν′2. as mentioned in this paper showed that the bending potential function is expressed as a rapidly converging Taylor series expansion about the linear configuration.About:
This article is published in Chemical Physics Letters.The article was published on 1973-09-01. It has received 100 citations till now.read more
Citations
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Journal ArticleDOI
Time-resolved fluorescence of NO 2 in a magnetic field
TL;DR: In this article, the influence of magnetic field on the fluorescence of NO2 has been studied by time-resolved experiments and a simple model based on an expanded two-level approximation has been proposed.
Journal ArticleDOI
Fluorescence of NO2 in the 2 2B2 state and its application to the optical–optical double resonance (OODR) study of the complex visible spectrum
TL;DR: In this article, the fluorescence of NO2 in the 2'2B2 state, which is located at 1.86 eV above the dissociation limit (D0=3.12 eV), has been observed for the first time.
Journal ArticleDOI
Resonances and fluctuations in the unimolecular reaction of NO2
TL;DR: In this paper, the authors examined fluctuations and oscillations in the unimolecular reaction of NO2 and their manifestations in photofragment yield (PHOFRY) spectra, NO rotational state distributions and decomposition rates and showed that extraction of rates from linewidths in stateselected spectra is unjustified in the regime of overlapping resonances.
Journal ArticleDOI
Nitrogen dioxide fluorescence from N2O5 photolysis
TL;DR: Sugimoto et al. as discussed by the authors measured the visible fluorescence spectrum of nitrogen dioxide (photolysis induced fluorescence, PIF), and this spectrum was compared with monochromatically excited NO2 fluorescence spectra.
Journal ArticleDOI
Intersystem Crossing and Nonadiabatic Product Channels in the Photodissociation of N2O4 at 193 nm
TL;DR: In this article, velocity and angular distribution measurements of the products of N2O4 photodissociated at 193 nm were presented, showing evidence for only N−N bond fission.
References
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Journal ArticleDOI
Determination of Molecular Structure from Microwave Spectroscopic Data
TL;DR: In this article, a method for determining the position of an atom in a molecule from spectroscopic measurements on two isotopic species of the molecule is described, and explicit expressions are derived for linear, symmetric top, planar, and nonplanar asymmetric top molecules.
Journal ArticleDOI
Microwave Spectrum of NO2: Fine Structure and Magnetic Coupling
George R. Bird,James C. Baird,Albert W. Jache,Jimmie A. Hodgeson,Robert F. Curl,Albert C. Kunkle,James W. Bransford,John Rastrup‐Andersen,Jack Rosenthal +8 more
TL;DR: The results obtained for 14N16O2 are: Rotational constantsA=239 868.7±11 Mc/secB= 13 000.12±0.6 Mc/ secC= 12 303.45±0 6.6Mc/secOdd electron expectation values with respect to (3ra2−1)/2r3〉=−1.73×1024cm−3N−nucleus〈(rb−irc)2/r3
Journal ArticleDOI
The absorption spectrum of no2 in the 3 700-4 600 a region,
A. E. Douglas,K. P. Huber +1 more
TL;DR: In this article, an investigation of the absorption spectra of both 14NO2 and 15NO2 has revealed a long progression of red-degraded bands in the region 3 700 −4 600 A.
Journal ArticleDOI
Electronic Structure and Electronic Spectrum of Nitrogen Dioxide. III Spectral Interpretation
R. A. Gangi,L. Burnelle +1 more
TL;DR: In this article, the excitation energies, potential energy surfaces, and oscillator strengths computed in the previous paper are discussed in light of experimentally reported spectroscopic data, namely absorption, fluorescence, chemiluminescence, predissociation, photolysis, and the absence of phosphorescence.