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Journal ArticleDOI

The Determination of Heats of Adsorption by Gas-Solid Chromatography

S. A. Greene, +1 more
- 01 Jan 1958 - 
- Vol. 62, Iss: 1, pp 55-58
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This article is published in The Journal of Physical Chemistry.The article was published on 1958-01-01. It has received 96 citations till now. The article focuses on the topics: Adsorption.

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Zeolitic imidazolate framework-8 nanocrystal coated capillary for molecular sieving of branched alkanes from linear alkanes along with high-resolution chromatographic separation of linear alkanes.

TL;DR: A zeolitic imidazolate framework-8 (ZIF-8) nanocrystal coated capillary is shown not only to have a strong ability to sieve branched alkanes from linear alkane isomers but also to offer excellent features for high-resolution gas chromatographic separation oflinear alkanes due to van der Waals interaction between linear alkanes and the hydrophobic inner surfaces of the micropores.
Journal ArticleDOI

Introduction into the characterisation of porous materials by inverse gas chromatography.

TL;DR: The methods and parameters to be discussed include isotherm determination, the measurement of surface and free energy as well as the calculation of acid-base parameters, which allow for a study of thermodynamic and kinetic information.
Journal ArticleDOI

Effect of surface heterogeneity on adsorption on solid surfaces. Application of inverse gas chromatography in the studies of energetic heterogeneity of adsorbents.

TL;DR: In this article, a literature review of the chromatographic methods used for investigations of the heterogeneity of solid surfaces is presented, with special attention paid to inverse gas chromatography (IGC).
Journal ArticleDOI

HKUST-1 as an open metal site gas chromatographic stationary phase—capillary preparation, separation of small hydrocarbons and electron donating compounds, determination of thermodynamic data

TL;DR: In this paper, the development of cyclic preparation techniques based on the application of an SBU (secondary building unit) precursor and a linker solution for the generation of MOF (metal-organic framework) coatings were used to prepare HKUST-1 (Hong Kong University of Science and Technology-1) coated capillary gas-chromatographic columns.
Journal ArticleDOI

Chemisorption of probe molecules on metal oxides

TL;DR: In this article, the most sensitive probe of catalysts performance will continue to be the rate and selectivity of a chemical reaction, however, these macroscopic observations, adequate for determining how good a catalyst is, require supplementary microscopic information to remove ambiguity in the deduction of a catalytic mechanism.
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