Journal ArticleDOI
The dipole moment of the C—H bond
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This article is published in Transactions of The Faraday Society.The article was published on 1942-01-01. It has received 144 citations till now. The article focuses on the topics: Bond dipole moment & Transition dipole moment.read more
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Vibrational intensities in methane
TL;DR: In this paper, the absorption intensities of the two infra-red active vibrations in methane have been obtained from a perturbation calculation on the equilibrium wave functions derived in the preceding paper.
Journal ArticleDOI
Some theoretical considerations about vibrational band intensities
TL;DR: In this article, it is shown that the transverse moment of a bond appears sometimes to contribute almost as much as any of the other factors to the total change of total molecular dipole moment.
Journal ArticleDOI
The Infrared Dispersion of Acetylene and the Dipole Moment of the C-H Bond
TL;DR: In this paper, the contributions of the molecular vibrations to the index of refraction of acetylene have been determined and interpreted in terms of effective charges on the constituent atoms, and a comparison of these results with previous work indicates a possible regularity in the C-H bond moment in going from methane to ethylene to acetylene, although the regularity may only apparent.
Journal ArticleDOI
Are Molecular Orbitals Delocalized
TL;DR: In contrast to statements in a recent article in this Journal, the bonding electrons in methane can be properly described in terms of localized electrons, and photoelectron spectroscopy does not indicate otherwise.
Journal ArticleDOI
Electrically Induced Perturbations of Halogen Nuclear Quadrupole Interactions in Polycrystalline Compounds. II. Microscopic Theory
R. W. Dixon,N. Bloembergen +1 more
TL;DR: In this paper, the physical origins of electrically induced perturbations of quadrupole couplings in molecular solids are considered, and it is concluded that polarizations of bonding electrons near the resonant nuclei are of dominant importance in determining the magnitudes of the electric induced shifts.