Open AccessJournal Article
The first unsimmetrically substituted ring-tilted silicon-bridged [1]ferrocenophane
TLDR
In this paper, the structure analysis of (1, 1'-ferrocenediyl)methylphenylsilane, [Fe(C 17 H 16 Si)], is the first such study of an unsymmetrically substituted silicon-bridged [1]ferrocenophane.Abstract:
The structure analysis of the title compound, (1, 1'-ferrocenediyl)methylphenylsilane, [Fe(C 17 H 16 Si)], is the first such study of an unsymmetrically substituted silicon-bridged [1]ferrocenophane. The strain present in this molecule results in a tilting of the cyclopentadienyl rings by 21.0 (2)° from being parallelread more
Citations
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Journal ArticleDOI
Polyferrocenylsilane-based polymer systems.
Vasilios Bellas,Matthias Rehahn +1 more
TL;DR: It is conceivable that PFS-related platforms might be indispensable nano-objects in the near future, as they stand on the verge of a new generation of sophisticated materials.
Journal ArticleDOI
Strained metallocenophanes and related organometallic rings containing π-hydrocarbon ligands and transition-metal centers
TL;DR: This Review summarizes the current state of knowledge on the preparation, structural characterization, electronic structure, and reactivity of strained organometallic rings with pi-hydrocarbon ligands and d-block metals.
Journal ArticleDOI
Polyferrocenylsilan-basierte Polymersysteme
Vasilios Bellas,Matthias Rehahn +1 more
TL;DR: In this article, ausgehend wurden unterschiedlichste weiterfuhrende Synthesestrategien ausgearbeitet, die Zugang zu einer breiten Palette an Copolymeren, Polyelektrolyten und nanostrukturierten Materialien eroffnen.
Journal ArticleDOI
Gespannte Metallocenophane und ähnliche metallorganische Ringe mit π‐Kohlenwasserstoffliganden und Übergangsmetallzentren
TL;DR: In this paper, the authors discuss gespannte metallorganische Verbindungen with Ubergangsmetallzentren, π-Kohlenwasserstoffliganden, Brucken, and d-Block-Metallen.
Journal ArticleDOI
Thermal ring-opening polymerization of an unsymmetrical silicon-bridged [1]ferrocenophane in coordination nanochannels
TL;DR: Thermal ring-opening polymerization of the unsymmetrically substituted ferrocenophane was performed in one-dimensional nanochannels of porous coordination polymers (PCPs), and the tacticity of the resulting polymer was dependent on the pore size of PCPs.
References
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Journal ArticleDOI
Polyferrocenylsilane-based polymer systems.
Vasilios Bellas,Matthias Rehahn +1 more
TL;DR: It is conceivable that PFS-related platforms might be indispensable nano-objects in the near future, as they stand on the verge of a new generation of sophisticated materials.
Journal ArticleDOI
Strained metallocenophanes and related organometallic rings containing π-hydrocarbon ligands and transition-metal centers
TL;DR: This Review summarizes the current state of knowledge on the preparation, structural characterization, electronic structure, and reactivity of strained organometallic rings with pi-hydrocarbon ligands and d-block metals.
Journal ArticleDOI
Polyferrocenylsilan-basierte Polymersysteme
Vasilios Bellas,Matthias Rehahn +1 more
TL;DR: In this article, ausgehend wurden unterschiedlichste weiterfuhrende Synthesestrategien ausgearbeitet, die Zugang zu einer breiten Palette an Copolymeren, Polyelektrolyten und nanostrukturierten Materialien eroffnen.
Journal ArticleDOI
Gespannte Metallocenophane und ähnliche metallorganische Ringe mit π‐Kohlenwasserstoffliganden und Übergangsmetallzentren
TL;DR: In this paper, the authors discuss gespannte metallorganische Verbindungen with Ubergangsmetallzentren, π-Kohlenwasserstoffliganden, Brucken, and d-Block-Metallen.
Journal ArticleDOI
Thermal ring-opening polymerization of an unsymmetrical silicon-bridged [1]ferrocenophane in coordination nanochannels
TL;DR: Thermal ring-opening polymerization of the unsymmetrically substituted ferrocenophane was performed in one-dimensional nanochannels of porous coordination polymers (PCPs), and the tacticity of the resulting polymer was dependent on the pore size of PCPs.