Journal ArticleDOI
The influence of a trace amount of nitrobenzene on racemization of [Fe(phen)3]2+ and [Ni(phen)3]2+ in aqueous solution
TLDR
In this article, the association constants of the metal chelate ions with nitrobenzene in water were determined using the solubility of NitrobenZene in their aqueous solutions.About:
This article is published in Inorganica Chimica Acta.The article was published on 1980-01-01. It has received 5 citations till now. The article focuses on the topics: Nitrobenzene & Racemization.read more
Citations
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Journal ArticleDOI
The reactions of nucleophiles with complexes of chelating heterocyclic imines : a critical survey
TL;DR: Etude des reactions des coordinats libres, des complexes plan carre and des complexes octaedriques as discussed by the authors, a.k.a. complexes octahedriques
Journal ArticleDOI
Effect of Lattice Anions on the Racemization of Optically Active Metal Chelate Salts in the Solid State. 2. [Co(phen)3]X3, [Co(phen)2(en)]X3, and [Co(phen)(en)2]X3, Where X−=Cl−, Br−, or I−
TL;DR: In this article, the first-order racemization of anhydrous complexes was examined in the solid state, where a rapid initial loss of optical activity was observed for the complex salts.
Book ChapterDOI
Substitution Reactions of Inert Metal Complexes—Coordination Numbers 6 and Above: Cobalt
TL;DR: A general discussion of the chemistry of cobalt(III) complexes covering the 1981 literature can be found in this article, with an excellent review by Tobe(2) on the base hydrolysis of metal complexes.
Journal ArticleDOI
Accelerating Effect of Donor Solvents on Racemization of the Tris(1,10-phenanthroline)iron(II) Cation
TL;DR: In this article, a tris(1,10-phenanthroline)iron(II) cation, [Fe(phen)3]2+, has been measured at 7.5 °C to 17.5°C in 1,2-dichloroethane solutions of the iron complex, with donor solvents consisting of dimethyl sulfoxide (DMSO), N,N-dimethylformamide (DMF), methanol (MeOH), acetone (Ac), and acetonitrile (AN).
References
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Journal ArticleDOI
The Solubility of Aromatic Hydrocarbons in Water1
Robert L. Bohon,W. F. Claussen +1 more
Journal ArticleDOI
The rates of racemization and dissociation of the tris(1,10-phenanthroline)iron(II) cation in various solvents
F. M. Van Meter,H. M. Neumann +1 more
Journal ArticleDOI
The kinetics of racemization of optically active complex ions of group 8 elements. Part 2. The tris-(1:10 phenanthroline) and tris-(2:2′ dipyridyl) iron II and tris-(2:2′ dipyridyl) nickel II ions
N. R. Davies,F. P. Dwyer +1 more
Journal ArticleDOI
Conductance of tris(1,10-phenanthroline)iron(II) and tris(2,2'-bipyridine)iron(II) halides and perchlorates in water and nitrobenzene in relation to solvent extraction of the ion pairs
TL;DR: In this paper, the conductances of tris(l,10-phenanthroline)iron(II) and tris2,2'-bipyridine)-iron (II) chlorides, bromides, iodides, and perchlorates were measured in water and nitrobenzene at 25°.
Related Papers (5)
Electrode reaction of tris(1,10-phenanthroline)iron(II) complex in aqueous and non-aqueous solvents
Kotaro Ogura,Kuniko Miyamoto +1 more