Journal ArticleDOI
The influence of surface roughness of solid electrodes on electrochemical measurements
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In this paper, the influence of surface roughness of solid electrodes on electrochemical measurements is examined and a model and its mathematical consequences are presented which describe the effects in at least a semi-quantitative way.About:
This article is published in Electrochimica Acta.The article was published on 1965-02-01. It has received 411 citations till now. The article focuses on the topics: Surface roughness.read more
Citations
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The analysis of electrode impedances complicated by the presence of a constant phase element
TL;DR: In this article, it was shown that the electrical double-layer at a solid electrode does not in general behave as a pure capacitance but rather as an impedance displaying a frequency-independent phase angle different from 90°.
Book
Electrochemical Impedance Spectroscopy and its Applications
TL;DR: In this paper, the fundamental processes of diffusion and faradaic reaction at electrodes are discussed and a review of the applications of these processes can be found in a forthcoming volume in this series.
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AC and DC study of the temperature effect on mild steel corrosion in acid media in the presence of benzimidazole derivatives
TL;DR: In this paper, the effect of benzimidazole derivatives on mild steel corrosion in 1 M HCl at five different temperatures has been studied and the inhibiting efficiency and apparent activation energy have been calculated in the presence and in the absence of the organic inhibitors.
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Electrolyte-gated transistors for organic and printed electronics
Se Hyun Kim,Kihyon Hong,Wei Xie,Keun Hyung Lee,Sipei Zhang,Timothy P. Lodge,C. Daniel Frisbie +6 more
TL;DR: Recent progress in the development of electrolyte-gated transistors (EGTs) for organic and printed electronics is summarized and key developments in electrolyte materials for use in printed electronics are reviewed.
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A review of impedance plot methods used for corrosion performance analysis of painted metals
TL;DR: In this article, a small library of Bode and Nyquist plot shapes is presented, based on increasingly more complex equivalent electrical circuit models, along with methods for obtaining equivalent circuit component values.
References
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Journal ArticleDOI
On porous electrodes in electrolyte solutions—IV
TL;DR: In this paper, a simple theory proposed on the basis of a transmission-line model is shown to account fully for the ac behaviour of a brush electrode, and the rate-determining process at such an electrode may conveniently be studied either by direct comparison with theoretical predictions for a pore or by using a squared representation, leading to the same plots as obtained from flat electrodes.
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Determination of the Faradaic Impedance at Solid Electrodes and the Electrodeposition of Copper
J. O'm. Bockris,Brian E. Conway +1 more
TL;DR: In this article, the double layer capacity and resistance at copper interfaces in H2SO4 and in CuSO4 solution over a considerable potential range have been made at frequencies from 10 to 2000 cps.
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Mechanism of Electrolytic Silver Deposition and Dissolution
W. Mehl,J. O'm. Bockris +1 more
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On impedance measurements: The determination of the double layer capacitance in the presence of an electrode reaction☆
TL;DR: In this article, a graphical method is given for the determination of both the double layer capacitance and the faradaic impedance from impedance measurements in the presence of a Faradaic process.
On impedance measurements: the determination of the double layer capacitance in the presence of an electrode reaction; and capillary response at a dropping mercury electrode.
TL;DR: In this paper, a graphical method for obtaining the true double layer capacitance is presented, and a model is given which represents the electrical characteristics of the solution film inside the capillary is the principal locus of shielding at a DME.