Journal ArticleDOI
The infrared absorption spectra of metal acetylacetonates
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TLDR
In this article, an analysis of the spectral properties of metal derivatives of acetylacetone has been carried out in the region of 5000-290 cm −1 for twenty-four metal derivatives.About:
This article is published in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy.The article was published on 1961-01-01. It has received 84 citations till now. The article focuses on the topics: Metal L-edge & Metal K-edge.read more
Citations
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Structure and reactivity of alkali metal enolates
Lloyd M. Jackman,Barry C. Lange +1 more
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Electronic structure, spectra and magnetic properties of oxycations—IV ligation effects on the infra-red spectrum of the vanadyl ion
TL;DR: In this article, vanadium-oxygen multiple bond stretching frequencies have been tabulated for fifty-one oxovanadium(IV) and three vanadium(V) compounds.
Journal ArticleDOI
Infrared spectra of metal β-ketoenolates and related complexes
TL;DR: In this article, the authors present des frequences IR caracteristiques de complexes metalliques de degre d'oxydation II and de luranyle avec des derives cetoniques: tautomerie, substitution de coordinat, formation de compose d'addition.
Infrared spectra of metal p-ketoenolates and related complexes
TL;DR: In this article, the assignment problem of metal/I-ketoenolates is considered. But the assignment is not addressed in this paper, since it is assumed that one or both 0 atoms have been substituted by NH, S or Se.
References
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Journal ArticleDOI
Electronic properties of transition-metal oxides—I: Distortions from cubic symmetry
Jack D. Dunitz,L. E. Orgel +1 more
TL;DR: In this paper, the distortions from cubic symmetry which occur in certain transition-metal oxides, particularly those with the spinel structure, are discussed in terms of crystal (ligand) field theory and it is shown that many such distortions, including all the large ones, are related in a simple fashion to the electronic configuration of the metal ion.
Journal ArticleDOI
Infrared Spectra of Metal‐Chelate Compounds. I. A Normal Coordinate Treatment on Bis‐(Acetylacetonato)‐Cu(II)
Kazuo Nakamoto,Arthur E. Martell +1 more
TL;DR: In this article, a normal coordinate treatment on the chelate ring of bis(acetylacetonato)•Cu(II) gives calculated frequencies in good agreement with the observed ones in the 1700 and 350 cm-1 range obtained with NaCl, KBr, and CsBr optics.
Journal ArticleDOI
Infrared Absorption of Metal Chelate Compounds of 1,3-Diketones1
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Paramagnetic Resonance in Trivalent Transition Metal Complexes
TL;DR: In this article, the symmetry of the field perturbing the metal ion is predominantly axial and the axial potential is negative for the complexes of Ti+3 and of Ru+3.
Related Papers (5)
Infrared Spectra of Metal‐Chelate Compounds. I. A Normal Coordinate Treatment on Bis‐(Acetylacetonato)‐Cu(II)
Kazuo Nakamoto,Arthur E. Martell +1 more