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Journal ArticleDOI

The infrared spectrum of ozone

David J. McCaa, +1 more
- 01 Mar 1968 - 
- Vol. 25, Iss: 3, pp 374-397
TLDR
In this article, 14 bands of ozone between 500 and 3300 cm −1 have been identified and values of the vibrational anharmonic constants determined and the integrated band absorptances of many of these bands have been measured from spectra of a 32-m path of ozone-oxygen mixtures containing up to 30 atm cm O ǫ near 25°C.
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This article is published in Journal of Molecular Spectroscopy.The article was published on 1968-03-01. It has received 91 citations till now. The article focuses on the topics: Spectral bands.

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Citations
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Journal ArticleDOI

AFGL atmospheric absorption line parameters compilation: 1982 edition.

TL;DR: The latest edition of the AFGL atmospheric absorption line parameters compilation for the seven most active infrared terrestrial absorbers is described and the sources of the absorption parameters are summarized.
Journal ArticleDOI

Coriolis interaction and anharmonic potential function of ozone from the microwave spectra in the excited vibrational states

TL;DR: In this article, the microwave absorption spectra of ozone were identified in the excited vibrational states with v1 = 1, v2 = 1 and 2, and v3 = 1.
Journal ArticleDOI

Infrared spectra of 16O3 and 18O3: Darling and Dennison resonance and anharmonic potential function of ozone

TL;DR: In this article, the analysis of thirty-three vibrotational bands permits the observation of Darling and Dennison resonance and gives harmonic frequencies (cm−1): 16 ω 1 = 1134.9, 18 ω 2 = 716.0, 674.5, potential and force constants are calculated through second order.
Journal ArticleDOI

Molecular line parameters for the atmospheric trace molecule spectroscopy experiment

TL;DR: This paper describes the spectroscopic line parameter database compiled for the ATMOS experiment and referenced in other papers describing ATMOS results, and catalogs parameters of 46 minor and trace species in the 1–10,000-cm−1 region.
Journal ArticleDOI

Potential energy surfaces of ozone in its ground state and in the lowest-lying eight excited states

TL;DR: In this paper, the potential energy surfaces of the ground state and the lowest eight excited states of ozone were calculated employing multireference contiguration interaction (MRD-CI) treatments in a Gaussian A0 basis.
References
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Journal ArticleDOI

A statistical model for water-vapour absorption

TL;DR: In this paper, a statistical model of a water-vapour absorption band is discussed, and comparison with computations made by Cowling shows that it provides a very accurate account of the average transmission over narrow frequency bands.
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Models for Spectral Band Absorption

TL;DR: In this article, an exhaustive theoretical study of the various models that have been proposed to represent band absorption is made; a derivation is given of the regions where they predict the same absorption.
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Absorption Line Broadening in the Infrared

TL;DR: In this article, the effects of various gases on the absorption bands of nitrous oxide, carbon monoxide, methane, carbon dioxide, and water vapor have been investigated; the results are expressed in terms of relative foreign broadening coefficients and relative collision diameters.
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Useful Representations for Measurements of Spectral Band Absorption

TL;DR: In this article, three different methods are discussed for the representation of laboratory measurements of spectral band absorption, and the regions of validity of each of these approximations are given for the Elsasser and statistical models.
Journal ArticleDOI

Infrared Transmission of Synthetic Atmospheres.* I. Instrumentation

TL;DR: In this paper, a technique for investigation of the infrared absorption of water vapor and carbon dioxide under simulated atmospheric conditions has been developed, which includes a 22m multiple-traversal absorption cell which permits controlled variation of the following parameters: (1) geometrical path length, pressure of absorbing gas, (2) pressure of nonabsorbing gases nitrogen and oxygen, and (3) the temperature of the gaseous mixture.
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