Journal ArticleDOI
The isolation and x-ray crystal structure of a complex between sodium hexafluorophosphate and dibenzo-36-crown-12
TLDR
The crystal structure of 2NaPF6·dibenzo-36crown-12 was determined by X-ray diffraction methods as discussed by the authors, and the 2:1 (metal:ligand) complex crystallises in the monoclinic system, space group P21/n with cell constants of a = 14.189(2), b = 9.372(1), c = 16.750(3) A, and β = 108.98°.About:
This article is published in Polyhedron.The article was published on 1984-01-01. It has received 9 citations till now. The article focuses on the topics: Monoclinic crystal system & Sodium hexafluorophosphate.read more
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First- and second-sphere coordination chemistry of alkali metal crown ether complexes
TL;DR: In this paper, the structural chemistry of first and second-sphere alkali metal cation complexes of crown ethers is examined with an emphasis on the role played by hydrogen bonding interactions to counter anions and other co-ligands such as water.
Journal ArticleDOI
Big and little Meccano
TL;DR: The emergence of the mechanical bond during the past 25 years is giving chemistry a fillip in more ways than one as discussed by the authors, and it is providing a new lease of life to chemical synthesis where mechanical bond formation occurs as a consequence of the all-important templation orchestrated by molecular recognition and self-assembly.
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Comprehensive coordination chemistry of alkali and alkaline earth cations with macrocyclic multidentates: latest position
Amritlal V. Bajaj,N. S. Poonia +1 more
Journal ArticleDOI
Das erste koordinativ gesättigte, viersträngige Helicat und seine Einschlußverbindung mit einem Hexafluorophosphation
David A. McMorran,Peter J. Steel +1 more
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Koordination in zweiter Sphäre — eine neuartige Rolle für Rezeptormoleküle
TL;DR: In this paper, aufgebot an nicht-kovalenten Bindungen-einschlieslich elektrostatischer Krafte, Wasserstoffbruckenbindungen, Charge-Transfer-and van-der-Waals-Wechselwirkungen is presented.
References
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Journal ArticleDOI
Binuclear copper(II) "face to face" inclusion complex of a macrotricyclic ligand
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Cryptates with macrotricyclic ligands. The structure of the sodium [3]-cryptate [(C32H64N4O10)Na2]I2
TL;DR: In this paper, the tricyclic ligand C 32 H 64 N 4 O 10 was determined from diffractometer data by the heavy atom method and refined by least-squares to R(F) = 0.057 for 1927 reflections.