Journal ArticleDOI
The Mechanism of the Reaction of Silver Nitrite with Alkyl Halides. The Contrasting Reactions of Silver and Alkali Metal Salts with Alkyl Halides. The Alkylation of Ambident Anions1,2
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This article is published in Journal of the American Chemical Society.The article was published on 1955-12-01. It has received 248 citations till now. The article focuses on the topics: Silver nitrite & Alkyl.read more
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Journal ArticleDOI
In-Situ Nitroxide-Mediated Radical Polymerization (NMP) Processes: Their Understanding and Optimization
TL;DR: High Molecular Weight Hydroxylamines for the Polymerization of Vinyl Monomers and Synthesis of Block Copolymers and Syntheses of BlockCopolymers.
Journal ArticleDOI
Substitution Reactions Which Proceed via Radical Anion Intermediates
TL;DR: It is of interest that a number of groups which do not behave as leaving groups in SN2 displacements are readily displaced at room temperature from a satureted carbon atom via the radical anion-free radical pathway, e.g., nitro, azide, sulfone, and ether groups.
Journal ArticleDOI
Farewell to the HSAB Treatment of Ambident Reactivity
TL;DR: It is demonstrated that the HSAB as well as the related Klopman-Salem model do not even correctly predict the behavior of the prototypes of ambident nucleophiles and, therefore, are rather misleading instead of useful guides.
Book ChapterDOI
Lösungsmittel und empirische Parameter zur Charakterisierung ihrer Polarität
Ch. Reichardt,Karl Dimroth +1 more
TL;DR: In den letzten Jahren, den Interesse an Losungsmittelproblemen is auserordentlich gestiegen as discussed by the authors, and die Entdeckung oft uberraschender Wirkungen von einzelnen Losungmittels auf den Verlauf chemischer Reaktionen oder auf die physikalischen Eigenschaften der in ihnen gelosten Verbindungen und das Bestreben des Chemikers, zu einem tieferen
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Application of the Principle of Hard and Soft Acids and Bases to Organic Chemistry
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