Journal ArticleDOI
The organometallic chemistry of phosphazenes
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This article is published in Polyhedron.The article was published on 1987-01-01. It has received 142 citations till now. The article focuses on the topics: Organometallic chemistry.read more
Citations
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Journal ArticleDOI
Cyclophosphazene-based multi-site coordination ligands
TL;DR: In this paper, a review of the recent developments in the design, assembly and utility of cyclophosphazene-based ligands is presented, where the reactive periphery of the chlorocyclophosphamide allows their ready elaboration into a variety of multi-site coordination ligands.
Journal ArticleDOI
Polyphosphazenes: Synthesis, structures, properties, applications
Ph. Potin,R. De Jaeger +1 more
TL;DR: The first polyphosphazene synthesis dates from the work of Allcock published in 1964 and since then, new synthetic routes have been developed, each of them characterized by specific advantages, viz. simplification, better control over molecular weights and cross-linking processes, possibility of substitution with alkyl or aryl groups.
Journal ArticleDOI
From neutral iminophosphoranes to multianionic phosphazenates. The coordination chemistry of imino–aza-P(V) ligands
TL;DR: In this paper, the chemistry and coordination behavior of imino-aza phosphorus(V) ligands focussing on s- and p-block as well as Group 11 and 12 metal complexes are discussed.
Book ChapterDOI
Advances in the chemistry of chlorocyclophosphazenes
TL;DR: In this article, the authors deal with chlorocyclophophosphazenes and their reactions, including the replacement of halogens on halogenocycloprophazenes by a variety of nucleophiles.
Journal ArticleDOI
Columnar mesomorphic organizations in cyclotriphosphazenes.
Joaquín Barberá,Manuel Bardají,Josefina Jiménez,Antonio Laguna,M Pilar Martínez,Luis Oriol,José Luis Serrano,Irene Zaragozano +7 more
TL;DR: A synthetic strategy has been developed to prepare cyclotriphosphazenes that bear polycatenar aromatic esters as promesogenic units linked to phosphorus atoms and all of the synthesized phosphazenes show a high thermal stability.
References
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Journal ArticleDOI
Polyphosphazene solid electrolytes
TL;DR: In this article, the phosphazene polymer (NP(OC2H40C2H4OCH3)n, MEEP, was synthesized and amorphous solvent-free salt complexes were performed with LiSo3CF3, NaSO3 CF3, Sr(SO 3CF3)2, and AgSO3cf3.25.
Journal ArticleDOI
Synthesis of High Polymeric Alkoxy- and Aryloxyphosphonitriles
Harry R. Allcock,R. L. Kugel +1 more
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